[p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂

Base Information

Chemical Name:[p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂
CAS No.:686274-20-4
Molecular Formula:C₃₀H₄₃F₆IrO₂P₂
Molecular Weight:803.828
Hs Code.:

[p-(3,5-CF<sub>3</sub>)2C<sub>6</sub>H<sub>3</sub>C<sub>6</sub>H<sub>2</sub>-2,6-(OP(tBu)2)2]IrH<sub>2</sub>

Synonyms:[p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂

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Chemical Property of [p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂

Chemical Property:

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Technology Process of [p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂

There total 5 articles about [p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 671789-64-3
[4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl

: 1333-74-0
hydrogen

: [p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₄

: 686274-20-4
[p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂

Guidance literature:: With tert-C₄H₉ONa; In benzene; byproducts: NaCl, t-BuOH; 1 equiv of complex and 1.1 equiv of NaOt-Bu were dissolved in N2-free benzene, the flask was purged with H2, the soln. was stirred for 0.5-1.5 hat 23°C under slow flow of H2; the mixt. was cooled to 0°C, the solvent was removed in vac. (1E-3 mbar, 3 h), Ar and N2-free pentane were added, filtered, the solvent was removed in vac., the residue was dissolved in N2-free C6H6, sublimed at 0°C for 2 h; elem. anal.;
DOI:10.1021/om030670o

Reference yield: 1.0%

: 671789-64-3
[4-(3,5-bis(trifluoromethyl)phenyl)C₆H₃-2,6-(OP(tBu)2)2]IrHCl

: 108-38-3,104809-90-7
m-xylene

: 686274-20-4
[p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂

: 686274-31-7
Ir(H)C₆H₃(CH₃)2(P(C₄H₉)2O)2C₆H₂C₆H₃(CF₃)2

Guidance literature:: With tert-C₄H₉ONa; In further solvent(s); a mixt. of complex and NaOBu-t in mesitylene-d12 and 2-3 equiv of m-xylene, 30-60 min at 23°C; not sepd., detected by NMR spectra;
DOI:10.1021/om030670o

Reference yield:

: 931-88-4,931-87-3,25267-51-0
cis-Cyclooctene

: 671789-64-3
IrHCl(C₆H₂(CF₃)2C₆H₃(OP(C(CH₃)3)2)2)

: 292-64-8
Cyclooctan

: 686274-20-4
[p-(3,5-CF₃)2C₆H₃C₆H₂-2,6-(OP(tBu)2)2]IrH₂

: 752245-69-5
Ir(C₆H₂(CF₃)2C₆H₃(OP(C(CH₃)3)2)2)C₈H₁₄

Guidance literature:: With sodium t-butanolate; In neat (no solvent); byproducts: NaCl, OHC(CH3)3; Sonication; cyclooctane and cyclooctene were added to mixt. of Ir-complex and NaOC(CH3)3 under Ar, shaken and treated with ultrasound for 30-60 min at 23°C;
DOI:10.1021/ja048393f