{1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-2-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]ethoxy}-tert-butyldimethylsilane

Base Information

Chemical Name:{1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-2-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]ethoxy}-tert-butyldimethylsilane
CAS No.:910488-43-6
Molecular Formula:C₃₄H₅₈O₆Si
Molecular Weight:590.916
Hs Code.:

Synonyms:{1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-2-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]ethoxy}-tert-butyldimethylsilane

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Chemical Property of {1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-2-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]ethoxy}-tert-butyldimethylsilane

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Technology Process of {1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-2-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]ethoxy}-tert-butyldimethylsilane

There total 14 articles about {1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-2-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]ethoxy}-tert-butyldimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 910488-42-5
9-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]-8-(tert-butyldimethylsilanyloxy)non-1-ene-4,6-diol

: 77-76-9
2,2-dimethoxy-propane

: 910488-43-6
{1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-2-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]ethoxy}-tert-butyldimethylsilane

Guidance literature:: With pyridinium p-toluenesulfonate; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/ol060812l

Reference yield:

: 910488-36-7
(4S)-6-(benzyloxy)-4-hydroxyhexan-2-one

: 910488-43-6
{1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-2-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]ethoxy}-tert-butyldimethylsilane

Guidance literature:: Multi-step reaction with 10 steps

1: 77 percent / SnCl₄ / CH₂Cl₂ / 1 h / -78 °C

2: 96 percent / PPTS / CH₂Cl₂ / 3 h / 20 °C

3: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

4: 185 mg / diethyl ether / 2 h / -78 °C

5: 89 percent / 2,6-lutidine / CH₂Cl₂ / 3 h / -78 °C

6: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

7: 0.738 g / Ti(S,S)(TADDOL) / diethyl ether / 1 h / -78 °C

8: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

9: 0.752 g / SnCl₄ / CH₂Cl₂ / 1 h / -78 °C

10: 97 percent / PPTS / CH₂Cl₂ / 3 h / 20 °C

With 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; Ti(S,S)(TADDOL); water; pyridinium p-toluenesulfonate; tin(IV) chloride; 2,6-dimethylpyridine; In 1,4-dioxane; diethyl ether; dichloromethane;
DOI:10.1021/ol060812l

Reference yield:

: 910488-37-8
(3S,5R)-1-benzyloxy-5-methyloct-7-ene-3,5-diol

: 910488-43-6
{1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-ylmethyl)-2-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]ethoxy}-tert-butyldimethylsilane

Guidance literature:: Multi-step reaction with 9 steps

1: 96 percent / PPTS / CH₂Cl₂ / 3 h / 20 °C

2: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

3: 185 mg / diethyl ether / 2 h / -78 °C

4: 89 percent / 2,6-lutidine / CH₂Cl₂ / 3 h / -78 °C

5: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

6: 0.738 g / Ti(S,S)(TADDOL) / diethyl ether / 1 h / -78 °C

7: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

8: 0.752 g / SnCl₄ / CH₂Cl₂ / 1 h / -78 °C

9: 97 percent / PPTS / CH₂Cl₂ / 3 h / 20 °C

With 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; Ti(S,S)(TADDOL); water; pyridinium p-toluenesulfonate; tin(IV) chloride; 2,6-dimethylpyridine; In 1,4-dioxane; diethyl ether; dichloromethane;
DOI:10.1021/ol060812l