methyl 2,6-diamino-3-[2-(tert-butyldimethylsilanyloxymethyl)furan-3-yl]benzoate

Base Information

Chemical Name:methyl 2,6-diamino-3-[2-(tert-butyldimethylsilanyloxymethyl)furan-3-yl]benzoate
CAS No.:1412976-07-8
Molecular Formula:C₁₉H₂₈N₂O₄Si
Molecular Weight:376.528
Hs Code.:

Synonyms:methyl 2,6-diamino-3-[2-(tert-butyldimethylsilanyloxymethyl)furan-3-yl]benzoate

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Chemical Property of methyl 2,6-diamino-3-[2-(tert-butyldimethylsilanyloxymethyl)furan-3-yl]benzoate

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Technology Process of methyl 2,6-diamino-3-[2-(tert-butyldimethylsilanyloxymethyl)furan-3-yl]benzoate

There total 4 articles about methyl 2,6-diamino-3-[2-(tert-butyldimethylsilanyloxymethyl)furan-3-yl]benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1356113-88-6
methyl 3-bromo-2,6-diaminobenzoate

: 1412976-09-0
2-(tert-butyldimethylsilanyloxymethyl)furan-3-boronic acid

: 1412976-07-8
methyl 2,6-diamino-3-[2-(tert-butyldimethylsilanyloxymethyl)furan-3-yl]benzoate

Guidance literature:: With caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In 1,4-dioxane; water; at 70 ℃; for 1.25h; Inert atmosphere;

Reference yield:

: 90050-54-7
methyl 6-amino-3-bromo-2-nitrobenzoate

: 1412976-07-8
methyl 2,6-diamino-3-[2-(tert-butyldimethylsilanyloxymethyl)furan-3-yl]benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: ethanol; iron / water; formic acid; acetic acid / 2 h / 20 °C

2: caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate / tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / 1,4-dioxane; water / 1.25 h / 70 °C / Inert atmosphere

With ethanol; iron; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In 1,4-dioxane; formic acid; water; acetic acid;

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 1412976-07-8
methyl 2,6-diamino-3-[2-(tert-butyldimethylsilanyloxymethyl)furan-3-yl]benzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: dichloromethane; pyridine / 1 h / 0 - 20 °C

2.1: n-butyllithium / hexane; diethyl ether / 2.5 h / -70 °C

2.2: 1.75 h / 20 °C

3.1: caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate / tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / 1,4-dioxane; water / 1.25 h / 70 °C / Inert atmosphere

With n-butyllithium; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In 1,4-dioxane; pyridine; diethyl ether; hexane; dichloromethane; water;