C₂₇H₃₈N₂

Base Information

• Chemical Name: C₂₇H₃₈N₂
• CAS No.: 1119821-66-7
• Molecular Formula: C₂₇H₃₈N₂
• Molecular Weight: 390.612
• Mol file: 1119821-66-7.mol

Synonyms:C₂₇H₃₈N₂

Chemical Property of C₂₇H₃₈N₂

Chemical Property:

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Technology Process of C₂₇H₃₈N₂

There total 1 articles about C₂₇H₃₈N₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

3,3-dimethyl-2-(2,6-dimethylphenylimino)butane (85385-10-0) + 1-chloro-2,2-dimethyl-1-(2,6-dimethylphenylimino)propane (57182-15-7) → C27H38N2 (1119821-66-7)

Guidance literature:

3,3-dimethyl-2-(2,6-dimethylphenylimino)butane; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In hexane; at 20 ℃; for 6h; Inert atmosphere;

1-chloro-2,2-dimethyl-1-(2,6-dimethylphenylimino)propane; In hexane; for 1h; Inert atmosphere; Reflux;

DOI:10.1002/anie.200804304

Reference yield: 80.0%

C27H38N2 (1119821-66-7) + trifluoroborane diethyl ether (109-63-7) → C27H37BF2N2 (1485825-68-0)

Guidance literature:

C₂₇H₃₈N₂; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 3h; Inert atmosphere; Schlenk technique;

trifluoroborane diethyl ether; In diethyl ether; at 20 ℃; for 72h; Inert atmosphere; Schlenk technique;

DOI:10.1021/om4008407

Reference yield:

C27H38N2 (1119821-66-7) → C27H37BN2

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane; diethyl ether / 3 h / -78 °C / Inert atmosphere; Schlenk technique

1.2: 72 h / 20 °C / Inert atmosphere; Schlenk technique

2.1: sodium naphthalenide / tetrahydrofuran / 168 h / 20 °C / Inert atmosphere; Schlenk technique

With n-butyllithium; sodium naphthalenide; In tetrahydrofuran; diethyl ether; hexane;

DOI:10.1021/om4008407

upstream raw materials:

3,3-dimethyl-2-(2,6-dimethylphenylimino)butane

1-chloro-2,2-dimethyl-1-(2,6-dimethylphenylimino)propane

Downstream raw materials:

C₂₇H₃₇BF₂N₂