(2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde

Base Information

Chemical Name:(2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde
CAS No.:370886-85-4
Molecular Formula:C₃₀H₄₄O₅Si
Molecular Weight:512.762
Hs Code.:

Synonyms:(2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde

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Chemical Property of (2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde

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Technology Process of (2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde

There total 10 articles about (2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 370886-85-4
(2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde

Guidance literature:: Multi-step reaction with 9 steps

1: 2,6-lutidine / CH₂Cl₂ / 0 °C

2: CSA / methanol; CH₂Cl₂ / 20 °C

3: 100 percent / Et₃N; DMAP / CH₂Cl₂ / 20 °C

4: TPAP; NMO; 4 Angstroem molecular sieves / CH₂Cl₂ / 20 °C

5: L-selectride / tetrahydrofuran / -78 °C

6: CSA / methanol; CH₂Cl₂ / 20 °C

7: NaH / dimethylformamide / 0 - 20 °C

8: OsO₄; NMO / acetone; H₂O / 20 °C

9: NaIO₄ / tetrahydrofuran; H₂O / 20 °C

With 2,6-dimethylpyridine; dmap; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; camphor-10-sulfonic acid; L-Selectride; sodium hydride; triethylamine; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0040-4039(01)01067-X

Reference yield:

: 1-((2S,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-ethane-1,2-diol

: 370886-85-4
(2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde

Guidance literature:: With sodium periodate; In tetrahydrofuran; water; at 20 ℃;
DOI:10.1016/S0040-4039(01)01067-X

Reference yield:

: (2R,4aR,6S,7R)-2-Phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

: 370886-85-4
(2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde

Guidance literature:: Multi-step reaction with 9 steps

1: 2,6-lutidine / CH₂Cl₂ / 0 °C

2: CSA / methanol; CH₂Cl₂ / 20 °C

3: 100 percent / Et₃N; DMAP / CH₂Cl₂ / 20 °C

4: TPAP; NMO; 4 Angstroem molecular sieves / CH₂Cl₂ / 20 °C

5: L-selectride / tetrahydrofuran / -78 °C

6: CSA / methanol; CH₂Cl₂ / 20 °C

7: NaH / dimethylformamide / 0 - 20 °C

8: OsO₄; NMO / acetone; H₂O / 20 °C

9: NaIO₄ / tetrahydrofuran; H₂O / 20 °C

With 2,6-dimethylpyridine; dmap; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; camphor-10-sulfonic acid; L-Selectride; sodium hydride; triethylamine; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0040-4039(01)01067-X