1-(13-Benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-{3,5-bis-[2-(13-benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-oxo-ethoxy]-phenoxy}-ethanone

Base Information

Chemical Name:1-(13-Benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-{3,5-bis-[2-(13-benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-oxo-ethoxy]-phenoxy}-ethanone
CAS No.:180966-06-7
Molecular Formula:C₆₉H₁₀₂N₆O₆S₆
Molecular Weight:1304
Hs Code.:

Synonyms:1-(13-Benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-{3,5-bis-[2-(13-benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-oxo-ethoxy]-phenoxy}-ethanone

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Chemical Property of 1-(13-Benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-{3,5-bis-[2-(13-benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-oxo-ethoxy]-phenoxy}-ethanone

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Technology Process of 1-(13-Benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-{3,5-bis-[2-(13-benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-oxo-ethoxy]-phenoxy}-ethanone

There total 10 articles about 1-(13-Benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-{3,5-bis-[2-(13-benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-oxo-ethoxy]-phenoxy}-ethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 108-73-6
3,5-dihydroxyphenol

: 180966-02-3
5-benzyl-1,9-dithia-13-chloroacetyl-5,13-diazacyclohexadecane

: 180966-06-7
1-(13-Benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-{3,5-bis-[2-(13-benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-oxo-ethoxy]-phenoxy}-ethanone

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; for 12h; Ambient temperature;
DOI:10.1039/p19960001553

Reference yield:

: 5279-23-2
3,3‘-(benzylazanediyl)bis(propan-1-ol)

: 180966-06-7
1-(13-Benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-{3,5-bis-[2-(13-benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-oxo-ethoxy]-phenoxy}-ethanone

Guidance literature:: Multi-step reaction with 5 steps

1: 92 percent / SOCl₂ / CH₂Cl₂ / 1.) room temp., overnight, 2.) reflux, 2 h

2: 58 percent / Cs₂CO₃ / dimethylformamide / 24 h / 85 °C

3: 96 percent / HCl / methanol / 1 h / Ambient temperature

4: 89 percent / Et₃N / tetrahydrofuran / 2 h / Ambient temperature

5: 87 percent / Cs₂CO₃ / dimethylformamide / 12 h / Ambient temperature

With hydrogenchloride; thionyl chloride; caesium carbonate; triethylamine; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/p19960001553

Reference yield:

: 102073-95-0
di-(3-chloropropyl)amine

: 180966-06-7
1-(13-Benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-{3,5-bis-[2-(13-benzyl-1,9-dithia-5,13-diaza-cyclohexadec-5-yl)-2-oxo-ethoxy]-phenoxy}-ethanone

Guidance literature:: Multi-step reaction with 7 steps

1: 77 percent / 10percent aq. NaOH / CH₂Cl₂ / 4 h

2: 80 percent / dimethylformamide / 48 h / Ambient temperature

3: 74 percent / NaOMe / methanol / 0.08 h

4: 58 percent / Cs₂CO₃ / dimethylformamide / 24 h / 85 °C

5: 96 percent / HCl / methanol / 1 h / Ambient temperature

6: 89 percent / Et₃N / tetrahydrofuran / 2 h / Ambient temperature

7: 87 percent / Cs₂CO₃ / dimethylformamide / 12 h / Ambient temperature

With hydrogenchloride; sodium hydroxide; sodium methylate; caesium carbonate; triethylamine; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/p19960001553