[1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol

Base Information

Chemical Name:[1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol
CAS No.:573693-16-0
Molecular Formula:C₅₄H₆₃NO₃Si₂
Molecular Weight:830.27
Hs Code.:

[1,6-bis-(<i>tert</i>-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9<i>H</i>-carbazol-4-yl]-methanol

Synonyms:[1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol

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Chemical Property of [1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol

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Technology Process of [1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol

There total 15 articles about [1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2203-80-7
5-methylhex-1-yne

: 573693-16-0
[1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol

Guidance literature:: Multi-step reaction with 3 steps

1.1: Cp₂ZrCl₂ / CH₂Cl₂ / 20 °C

1.2: 70 percent / I₂ / tetrahydrofuran; CH₂Cl₂ / 0 °C

2.1: t-BuLi / diethyl ether / -78 °C

2.2: Bu₃SnCl / diethyl ether / -78 - 20 °C

2.3: Pd(PPh₃)4 / toluene / 67 h / 110 °C

3.1: 100 percent / DIBAL / toluene / 2 h / 0 °C

With zirconocene dichloride; tert.-butyl lithium; diisobutylaluminium hydride; In diethyl ether; dichloromethane; toluene; 2.3: Stille coupling;
DOI:10.1039/b301979a

Reference yield:

: 6702-50-7
3-hydroxy-4-methoxybenzoate

: 573693-16-0
[1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol

Guidance literature:: Multi-step reaction with 7 steps

1.1: 100 percent / 2,6-lutidine / CH₂Cl₂ / 16 h / -10 - 20 °C

2.1: 62 percent / BINAP; Cs₂CO₃ / Pd(OAc)2 / toluene / 10 h / 100 °C

3.1: 43 percent / HOAc / Pd(OAc)2 / dioxane / 40 h / 100 °C

4.1: 77 percent / BBr₃ / CH₂Cl₂ / 120 h / -78 - 20 °C

5.1: 91 percent / ImH / dimethylformamide / 19 h / 70 °C

6.1: t-BuLi / diethyl ether / -78 °C

6.2: Bu₃SnCl / diethyl ether / -78 - 20 °C

6.3: Pd(PPh₃)4 / toluene / 67 h / 110 °C

7.1: 100 percent / DIBAL / toluene / 2 h / 0 °C

With 1H-imidazole; 2,6-dimethylpyridine; tert.-butyl lithium; boron tribromide; diisobutylaluminium hydride; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; acetic acid; palladium diacetate; In 1,4-dioxane; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene; 6.3: Stille coupling;
DOI:10.1039/b301979a

Reference yield:

: 7766-23-6
3-bromo-2-methylphenol

: 573693-16-0
[1,6-bis-(tert-butyl-diphenyl-silanyloxy)-8-(2,5-dimethyl-hex-1-enyl)-7-methyl-9H-carbazol-4-yl]-methanol

Guidance literature:: Multi-step reaction with 9 steps

1.1: 91 percent / KOH / dimethylsulfoxide / 1 h / 20 °C

2.1: 67 percent / claycop; Ac₂O / CCl₄ / 2.5 h / 20 °C

3.1: 91 percent / N₂H₄*H₂O; FeCl₃; activated carbon / methanol / 13 h / 65 °C

4.1: 62 percent / BINAP; Cs₂CO₃ / Pd(OAc)2 / toluene / 10 h / 100 °C

5.1: 43 percent / HOAc / Pd(OAc)2 / dioxane / 40 h / 100 °C

6.1: 77 percent / BBr₃ / CH₂Cl₂ / 120 h / -78 - 20 °C

7.1: 91 percent / ImH / dimethylformamide / 19 h / 70 °C

8.1: t-BuLi / diethyl ether / -78 °C

8.2: Bu₃SnCl / diethyl ether / -78 - 20 °C

8.3: Pd(PPh₃)4 / toluene / 67 h / 110 °C

9.1: 100 percent / DIBAL / toluene / 2 h / 0 °C

With 1H-imidazole; potassium hydroxide; tert.-butyl lithium; acetic anhydride; boron tribromide; iron(III) chloride; diisobutylaluminium hydride; pyrographite; caesium carbonate; copper(II) nitrate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; hydrazine hydrate; acetic acid; palladium diacetate; In 1,4-dioxane; methanol; tetrachloromethane; diethyl ether; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; 8.3: Stille coupling;
DOI:10.1039/b301979a