acetic acid [2-(4-methyl-5-oxo-3-cyclohexenyl)-2-propenyl] ester

Base Information

• Chemical Name: acetic acid [2-(4-methyl-5-oxo-3-cyclohexenyl)-2-propenyl] ester
• CAS No.: 56423-44-0
• Molecular Formula: C₁₂H₁₆O₃
• Molecular Weight: 208.257
• Mol file: 56423-44-0.mol

Synonyms:acetic acid [2-(4-methyl-5-oxo-3-cyclohexenyl)-2-propenyl] ester

Chemical Property of acetic acid [2-(4-methyl-5-oxo-3-cyclohexenyl)-2-propenyl] ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of acetic acid [2-(4-methyl-5-oxo-3-cyclohexenyl)-2-propenyl] ester

There total 1 articles about acetic acid [2-(4-methyl-5-oxo-3-cyclohexenyl)-2-propenyl] ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium acetate (127-09-3) + 5-[(1-chloromethyl)ethenyl]-2-methyl-2-cyclohexen-1-one (74514-31-1) → acetic acid [2-(4-methyl-5-oxo-3-cyclohexenyl)-2-propenyl] ester (56423-44-0)

Guidance literature:

With cetyltributylphosphonium bromide; In water; at 56 ℃; for 20h;

DOI:10.1021/jf010157q

Reference yield: 86.0%

acetic acid [2-(4-methyl-5-oxo-3-cyclohexenyl)-2-propenyl] ester (56423-44-0) → 5-[1-(hydroxymethyl)ethenyl]-2-methyl-2-cyclohexen-1-one (362483-07-6)

Guidance literature:

With potassium carbonate; at 20 ℃;

DOI:10.1021/jf010157q

Reference yield:

acetic acid [2-(4-methyl-5-oxo-3-cyclohexenyl)-2-propenyl] ester (56423-44-0) → α-methylene-4-methyl-5-oxo-3-cyclohexene-1-acetaldehyde (79763-05-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 86 percent / aq. K₂CO₃ / 20 °C

2: NaOCl; TEMPO; NaBr / CH₂Cl₂; H₂O / 0 °C

With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; potassium carbonate; sodium bromide; In dichloromethane; water;

DOI:10.1021/jf010157q

upstream raw materials:

sodium acetate

5-[(1-chloromethyl)ethenyl]-2-methyl-2-cyclohexen-1-one

Downstream raw materials:

5-[1-(hydroxymethyl)ethenyl]-2-methyl-2-cyclohexen-1-one

α-methylene-4-methyl-5-oxo-3-cyclohexene-1-acetaldehyde