l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate

Base Information

• Chemical Name: l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate
• CAS No.: 872359-33-6
• Molecular Formula: C₂₈H₄₁O₄PS
• Molecular Weight: 504.671
• Mol file: 872359-33-6.mol

Synonyms:l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate

Chemical Property of l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate

There total 2 articles about l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diisopropyl 2-(chlorosulfinyl)phenylphosphonate (872359-28-9) + (-)-8-phenylmenthol (65253-04-5) → l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate (872359-33-6)

Guidance literature:

diisopropyl 2-(chlorosulfinyl)phenylphosphonate; (-)-8-phenylmenthol; With trifluoroacetic anhydride; In tetrahydrofuran; at 20 ℃;

With triethylamine; In tetrahydrofuran; at -78 - 20 ℃;

DOI:10.1016/j.tetasy.2005.09.005

Reference yield:

diisopropyl (2-mercaptophenyl)phosphonate (149794-59-2) → l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate (872359-33-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sulfuryl chloride / CH₂Cl₂ / 0.5 h / 20 °C

2.1: trifluoroacetic anhydride / tetrahydrofuran / 20 °C

2.2: triethylamine / tetrahydrofuran / -78 - 20 °C

With sulfuryl dichloride; trifluoroacetic anhydride; In tetrahydrofuran; dichloromethane;

DOI:10.1016/j.tetasy.2005.09.005

Reference yield:

l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate (872359-33-6) → l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfinate + l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfinate

Guidance literature:

With (+)-(8,8-dichlorocamphorylsulfonyl)-oxaziridine; In tetrachloromethane; at 20 ℃; for 240h; Title compound not separated from byproducts;

DOI:10.1016/j.tetasy.2005.09.005

upstream raw materials:

diisopropyl 2-(chlorosulfinyl)phenylphosphonate

(-)-8-phenylmenthol

diisopropyl (2-mercaptophenyl)phosphonate