diisopropyl 2-(chlorosulfinyl)phenylphosphonate

Base Information

• Chemical Name: diisopropyl 2-(chlorosulfinyl)phenylphosphonate
• CAS No.: 872359-28-9
• Molecular Formula: C₁₂H₁₈ClO₃PS
• Molecular Weight: 308.766
• Mol file: 872359-28-9.mol

Synonyms:diisopropyl 2-(chlorosulfinyl)phenylphosphonate

Chemical Property of diisopropyl 2-(chlorosulfinyl)phenylphosphonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diisopropyl 2-(chlorosulfinyl)phenylphosphonate

There total 1 articles about diisopropyl 2-(chlorosulfinyl)phenylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diisopropyl (2-mercaptophenyl)phosphonate (149794-59-2) → diisopropyl 2-(chlorosulfinyl)phenylphosphonate (872359-28-9)

Guidance literature:

With sulfuryl dichloride; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1016/j.tetasy.2005.09.005

Reference yield:

diisopropyl 2-(chlorosulfinyl)phenylphosphonate (872359-28-9) + (-)-8-phenylmenthol (65253-04-5) → l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate (872359-33-6)

Guidance literature:

diisopropyl 2-(chlorosulfinyl)phenylphosphonate; (-)-8-phenylmenthol; With trifluoroacetic anhydride; In tetrahydrofuran; at 20 ℃;

With triethylamine; In tetrahydrofuran; at -78 - 20 ℃;

DOI:10.1016/j.tetasy.2005.09.005

Reference yield:

diisopropyl 2-(chlorosulfinyl)phenylphosphonate (872359-28-9) + methanol (67-56-1) → O-methyl 2-(diisopropoxyphosphoryl)benzenesulfenate

Guidance literature:

diisopropyl 2-(chlorosulfinyl)phenylphosphonate; methanol; With trifluoroacetic anhydride; In tetrahydrofuran; at 20 ℃;

With triethylamine; In tetrahydrofuran; at -78 - 20 ℃;

DOI:10.1016/j.tetasy.2005.09.005

upstream raw materials:

diisopropyl (2-mercaptophenyl)phosphonate

Downstream raw materials:

(-)-menthyl 2-(diisopropoxyphosphoryl)benzenesulfenate

(S)-bornyl 2-(diisopropoxyphosphoryl)benzenesulfenate

(1R,2S)-trans-2-phenyl-1-cyclohexyl 2-(diisopropoxyphosphoryl)benzenesulfenate

l-8-phenylmenthyl 2-(diisopropoxyphosphoryl)benzenesulfenate