5-<4-(9-hydroxy-1,4,7-trioxanonyl)phenyl>-10,15,20-triphenylporphyrin

Base Information

• Chemical Name: 5-<4-(9-hydroxy-1,4,7-trioxanonyl)phenyl>-10,15,20-triphenylporphyrin
• CAS No.: 130413-30-8
• Molecular Formula: C₅₀H₄₂N₄O₄
• Molecular Weight: 762.908
• Mol file: 130413-30-8.mol

Synonyms:5-<4-(9-hydroxy-1,4,7-trioxanonyl)phenyl>-10,15,20-triphenylporphyrin

Chemical Property of 5-<4-(9-hydroxy-1,4,7-trioxanonyl)phenyl>-10,15,20-triphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-<4-(9-hydroxy-1,4,7-trioxanonyl)phenyl>-10,15,20-triphenylporphyrin

There total 3 articles about 5-<4-(9-hydroxy-1,4,7-trioxanonyl)phenyl>-10,15,20-triphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

5-<4-(6-chloro-1,4-dioxahexyl)phenyl>-10,15,20-triphenylporphyrin (99521-97-8) + ethylene glycol (107-21-1) → 5-<4-(9-hydroxy-1,4,7-trioxanonyl)phenyl>-10,15,20-triphenylporphyrin (130413-30-8)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 100 ℃; for 5h;

Reference yield: 65.0%

2-[2-(chloroethoxy)ethoxy]ethanol (5197-62-6) + 5-(4'-hydroxyphenyl)-10,15,20-triphenylporphyrin (87345-22-0) → 5-<4-(9-hydroxy-1,4,7-trioxanonyl)phenyl>-10,15,20-triphenylporphyrin (130413-30-8)

Guidance literature:

With potassium hydroxide; In N,N-dimethyl-formamide; at 80 ℃; for 12h;

DOI:10.1002/(sici)1521-3773(19980504)37:8<1131::aid-anie1131>3.0.co;2-s

Reference yield:

5,10,15-triphenyl-20-(4-methoxyphenyl)-21H,23H-porphyrin → 5-<4-(9-hydroxy-1,4,7-trioxanonyl)phenyl>-10,15,20-triphenylporphyrin (130413-30-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 85 percent / BBr₃ / CH₂Cl₂ / 12 h / 0 °C

2: 65 percent / KOH / dimethylformamide / 12 h / 80 °C

With potassium hydroxide; boron tribromide; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1002/(sici)1521-3773(19980504)37:8<1131::aid-anie1131>3.0.co;2-s

upstream raw materials:

5-<4-(6-chloro-1,4-dioxahexyl)phenyl>-10,15,20-triphenylporphyrin

ethylene glycol

2-[2-(chloroethoxy)ethoxy]ethanol

5-(4'-hydroxyphenyl)-10,15,20-triphenylporphyrin

Downstream raw materials:

C₉₈H₇₈N₈O₆