(2S,3R,4R,5R)-3-hydroxy-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidine-2-carbaldehyde

Base Information

Chemical Name:(2S,3R,4R,5R)-3-hydroxy-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidine-2-carbaldehyde
CAS No.:1032325-86-2
Molecular Formula:C₂₉H₃₇NO₄SSi₂
Molecular Weight:551.854
Hs Code.:

Synonyms:(2S,3R,4R,5R)-3-hydroxy-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidine-2-carbaldehyde

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Chemical Property of (2S,3R,4R,5R)-3-hydroxy-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidine-2-carbaldehyde

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Technology Process of (2S,3R,4R,5R)-3-hydroxy-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidine-2-carbaldehyde

There total 1 articles about (2S,3R,4R,5R)-3-hydroxy-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidine-2-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 918107-49-0
(2S,3R,4R,5R)-2-(hydroxymethyl)-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidin-3-ol

: 1032325-86-2
(2S,3R,4R,5R)-3-hydroxy-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidine-2-carbaldehyde

Guidance literature:: With sodium hypochlorite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydrogencarbonate; potassium bromide; In dichloromethane; water; at 0 ℃; chemoselective reaction;
DOI:10.1002/chem.200701776

Reference yield:

: 1032325-86-2
(2S,3R,4R,5R)-3-hydroxy-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidine-2-carbaldehyde

: 762-72-1
allyl-trimethyl-silane

: 1032325-90-8
(2S,3R,4R,5R)-2-[(S)-1-hydroxybut-3-enyl]-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidin-3-ol

Guidance literature:: With titanium tetrachloride; In diethyl ether; at -78 ℃; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/chem.200701776

Reference yield:

: 1032325-86-2
(2S,3R,4R,5R)-3-hydroxy-4-[dimethyl(phenyl)silyl]-5-{[dimethyl(phenyl)silyl]methyl}-1-tosylpyrrolidine-2-carbaldehyde

: 1826-67-1
vinyl magnesium bromide

: C₃₁H₄₁NO₄SSi₂

: 1032325-88-4
C₃₁H₄₁NO₄SSi₂

Guidance literature:: In diethyl ether; at -100 ℃; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/chem.200701776