METHYL 2-[(CYANOMETHYL)SULFONYL]BENZOATE

Base Information

Chemical Name:METHYL 2-[(CYANOMETHYL)SULFONYL]BENZOATE
CAS No.:175137-52-7
Molecular Formula:C10H9 N O4 S
Molecular Weight:239.24800
Hs Code.:2926909090
Mol file:175137-52-7.mol

Synonyms:HMS554A17;methyl 2-[(cyanomethyl)sulfonyl]benzoate;mekthyl 2-(cyanomethylsulfonyl)benzoate;

Suppliers and Price of METHYL 2-[(CYANOMETHYL)SULFONYL]BENZOATE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
METHYL 2-[(CYANOMETHYL)SULFONYL]BENZOATE 95.00%
5MG
$ 500.74

Total 1 raw suppliers

Chemical Property of METHYL 2-[(CYANOMETHYL)SULFONYL]BENZOATE

Chemical Property:

Vapor Pressure:3.77E-09mmHg at 25°C
Boiling Point:473.9oC at 760 mmHg
Flash Point:240.4oC
PSA：92.61000
Density:1.336g/cm3
LogP:1.85128

Purity/Quality:: METHYL 2-[(CYANOMETHYL)SULFONYL]BENZOATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of METHYL 2-[(CYANOMETHYL)SULFONYL]BENZOATE

There total 3 articles about METHYL 2-[(CYANOMETHYL)SULFONYL]BENZOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 610-97-9
o-iodo-methyl-benzoic acid

: 1624363-23-0
3-azido-2-methylbut-3-en-2-ol

: 175137-52-7
methyl 2-((cyanomethyl)sulfonyl)benzoate

Guidance literature:: With 1,4-diazabicyclo [2.2.2] octane-1,4-diium-1,4-disulfinate; In acetonitrile; at 20 ℃; for 24h; Inert atmosphere; UV-irradiation;
DOI:10.1039/d0cc00351d

Reference yield:

: 67-56-1
methanol

: 2-cyanomethanesulfonyl-benzoyl chloride

: 175137-52-7
methyl 2-((cyanomethyl)sulfonyl)benzoate

Guidance literature:: at 60 ℃; for 0.75h; Yield given;
DOI:10.1002/jhet.5570360314

Reference yield:

: 147-93-3
Thiosalicylic acid

: 175137-52-7
methyl 2-((cyanomethyl)sulfonyl)benzoate

Guidance literature:: Multi-step reaction with 4 steps

1: 99 percent / aq. NaOH / 1 h / Ambient temperature

2: 83 percent / 35 percent aq. H₂O₂, AcOH / 6 h / 100 °C

3: thionyl chloride / 2 h / 60 °C

4: 0.75 h / 60 °C

With sodium hydroxide; thionyl chloride; dihydrogen peroxide; acetic acid;
DOI:10.1002/jhet.5570360314