(PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)}

Base Information

Chemical Name:(PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)}
CAS No.:93473-81-5
Molecular Formula:C₇H₅CoNO*C₃₆H₃₀NP₂
Molecular Weight:716.704
Hs Code.:

Synonyms:(PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)}

Suppliers and Price of (PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)}

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)}

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)}

There total 1 articles about (PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.6%

: 12078-25-0,12078-23-8
dicarbonylcyclopentadienylcobalt

: 65300-07-4
bis(triphenylphosphine)iminium cyanide

: 93473-81-5
(PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)}

Guidance literature:: In acetonitrile; Under N2, soln. of CpCo(CO)2 and (PPN)CN in CH3CN is left to stand for 2 d.; Evapn., crystn. from CH3CN/ether by cooling to -35°C for 1 d, filtn., washing of the red-brown crystals with ether, drying on the frit for 5 min, elem. anal..;

Reference yield: 49.0%

: 93473-81-5
(PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)}

: 639-58-7
triphenyltin chloride

: 114928-61-9
(η5-cyclopentadienyl)cobalt(CO)(triphenyltinisocyanide)*(PPN)Cl

Guidance literature:: In tetrahydrofuran; Under N2, cooled (-30°C) THF is added to cooled mixt. of (PPN)(CpCo(CN)(CO)) and SnPh3Cl, mixt. is stirred (1 h, slow temp. rise to -20°C, further 1 h, rise to room temp.), a pale red soln. with a white ppt. forms.; Cooling to -35°C, after 1 d filtn., evapn., recrystn. (hot THF, ether, several batches), recrystn. from hot THF, drying at 50°C for 1 d in vac., elem. anal..;

Reference yield: 7.0%

: 93473-81-5
(PPN){(η5-cyclopentadienyl)cobalt(cyanide)(CO)}

: 98-59-9
p-toluenesulfonyl chloride

: 114944-18-2
(PPN){(η5-cyclopentadienyl)cobalt(III)(cyanide)2(η1-tosyl)}

Guidance literature:: In tetrahydrofuran; Under N2, cooled soln. (-20°C) of tosyl chloride in THF is added to (PPN)(CpCo(CN)(CO)), mixt. is stirred at -20°C for 2 h , allowed to rise to room temp., stirred for 1 h.; Cooling to -35°C, after 1 d vac. filtn. yields red soln. and green oil, which solidifies when washed with ether. The solid is washed with CH3CN, orange residue is washed with ether and dried on the frit, recrystn. (CH3CN/ether), elem. anal..;