N-[2,6-bis(1-methylethyl)phenyl]-α-[ 2-(1-methylethyl)-phenyl]-6-(1-naphthalenyl)-2-pyridinemethanamine

Base Information

Chemical Name:N-[2,6-bis(1-methylethyl)phenyl]-α-[ 2-(1-methylethyl)-phenyl]-6-(1-naphthalenyl)-2-pyridinemethanamine
CAS No.:783341-93-5
Molecular Formula:C₃₇H₄₀N₂
Molecular Weight:512.738
Hs Code.:

Synonyms:N-[2,6-bis(1-methylethyl)phenyl]-α-[ 2-(1-methylethyl)-phenyl]-6-(1-naphthalenyl)-2-pyridinemethanamine

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Chemical Property of N-[2,6-bis(1-methylethyl)phenyl]-α-[ 2-(1-methylethyl)-phenyl]-6-(1-naphthalenyl)-2-pyridinemethanamine

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Technology Process of N-[2,6-bis(1-methylethyl)phenyl]-α-[ 2-(1-methylethyl)-phenyl]-6-(1-naphthalenyl)-2-pyridinemethanamine

There total 1 articles about N-[2,6-bis(1-methylethyl)phenyl]-α-[ 2-(1-methylethyl)-phenyl]-6-(1-naphthalenyl)-2-pyridinemethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 518058-51-0
2,6-bis(1-methylethyl)-N-[[6-(1-naphthalenyl)-2-pyridinyl]methylene]benzenamine

: 41285-22-7
2-isopropylphenyl lithium

: 783341-93-5
N-[2,6-bis(1-methylethyl)phenyl]-α-[ 2-(1-methylethyl)-phenyl]-6-(1-naphthalenyl)-2-pyridinemethanamine

Guidance literature:: 2,6-bis(1-methylethyl)-N-[[6-(1-naphthalenyl)-2-pyridinyl]methylene]benzenamine; 2-isopropylphenyl lithium; In diethyl ether; at 20 ℃; for 0.0666667 - 0.0833333h;

With water; ammonium chloride; In diethyl ether;

Reference yield: 80.0%

: 783341-93-5
N-[2,6-bis(1-methylethyl)phenyl]-α-[ 2-(1-methylethyl)-phenyl]-6-(1-naphthalenyl)-2-pyridinemethanamine

: 693-04-9
butyl magnesium bromide

: 13499-05-3
hafnium tetrachloride

: 869477-16-7
[Hf(C₄H₉)2(((CH₃)2CH)2C₆H₃NCH(C₆H₄CH(CH₃)2)(C₅H₃N)C₁₀H₆)]

Guidance literature:: With n-butyllithium; In hexane; toluene; (N2); Schlenk technique; soln. of BuLi/hexane added to soln. of ligand in toluene; stirred for 30 min; evapd. (vac.); hexane added; filtered; dissolved in toluene; HfCl4 added; refluxed (4 h); cooled; soln. of BuMgCl/Et2O (3.5 equiv.) added; stirred; evapd. (vac.); hexane added; filtered; washed (hexane); solvent removed (vac.);
DOI:10.1021/om900705v

Reference yield: 78.0%

: 783341-93-5
N-[2,6-bis(1-methylethyl)phenyl]-α-[ 2-(1-methylethyl)-phenyl]-6-(1-naphthalenyl)-2-pyridinemethanamine

: 75-16-1
methylmagnesium bromide

: 13499-05-3
hafnium tetrachloride

: [N-[2,6-bis(1-methylethyl)phenyl]-α-[2-(1-methylethyl)phenyl]-6-(1-naphthalenyl-κC2)-2-pyridinemethanaminato(2-)-κN1,κN2]dimethylhafnium

Guidance literature:: With CH₃CH₂CH₂CH₂Li; In diethyl ether; hexane; toluene; (N2); addn. of hexane soln. of butyllithium to toluene soln. of pyridinederiv., stirring for 1 h, addn. of HfCl4, heating at 100°C for 2 h, cooling, addn of ethereal soln. of magnesium compd., stirring overni ght at room temp.; evapn., addn. of toluene, filtration, washing with toluene, evapn., addn. of hexane, evapn., addn. of hexane, stirring for 30 min, filtration, washing with cold hexane, elem. anal.;
DOI:10.1021/om200167h