rac-(η5-pentamethylcyclopentadienyl)(1-benzyl-3-methyl-1,4,7-triphospha-cyclodecane)iron(II) hexafluorophosphate

Base Information

Chemical Name:rac-(η5-pentamethylcyclopentadienyl)(1-benzyl-3-methyl-1,4,7-triphospha-cyclodecane)iron(II) hexafluorophosphate
CAS No.:924366-80-3
Molecular Formula:C₂₅H₄₀FeP₃*F₆P
Molecular Weight:634.325
Hs Code.:

Synonyms:rac-(η5-pentamethylcyclopentadienyl)(1-benzyl-3-methyl-1,4,7-triphospha-cyclodecane)iron(II) hexafluorophosphate

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Chemical Property of rac-(η5-pentamethylcyclopentadienyl)(1-benzyl-3-methyl-1,4,7-triphospha-cyclodecane)iron(II) hexafluorophosphate

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Technology Process of rac-(η5-pentamethylcyclopentadienyl)(1-benzyl-3-methyl-1,4,7-triphospha-cyclodecane)iron(II) hexafluorophosphate

There total 1 articles about rac-(η5-pentamethylcyclopentadienyl)(1-benzyl-3-methyl-1,4,7-triphospha-cyclodecane)iron(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: ammonium hexafluorophosphate

: 924366-82-5
[(η5-pentamethylcyclopentadienyl)Fe(1,2-diphosphino-ethane)(benzyldiallylphosphine)][BF4]

: 924366-80-3
rac-(η5-pentamethylcyclopentadienyl)(1-benzyl-3-methyl-1,4,7-triphospha-cyclodecane)iron(II) hexafluorophosphate

Guidance literature:: With azoisobutyronitrile; In toluene; (N2); at 80°C for 72 h; evapd. (vac.), dissolved in CH2Cl2, chromd. (basic alumina, CH2Cl2, thenMeOH/CH2Cl2), re-chromd. as above, dissolved in MeOH, NH4PF6 and H2O ad ded, pptd. at 4°C overnight, filtered, washed (cold aq. MeOH), dried (vac.); elem. anal.;
DOI:10.1021/om060798g

Reference yield: 92.0%

: 75-09-2
dichloromethane

: 924366-80-3
rac-(η5-pentamethylcyclopentadienyl)(1-benzyl-3-methyl-1,4,7-triphospha-cyclodecane)iron(II) hexafluorophosphate

: 924366-84-7
rac-(η5-pentamethylcyclopentadienyl)(4,7-dichloro-1-benzyl-3-methyl-1,4,7-triphosphacyclodecane)iron(II) hexafluorophosphate

Guidance literature:: With NaOH; In dichloromethane; water; (N2); a soln. of Fe complex in CH2Cl2 stirred with aq. soln. of NaOH for1 h; the org. phase sepd., washed (H2O), dried (MgSO4), filtered, solvent-removed; elem. anal.;
DOI:10.1021/om060798g