fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV)

Base Information

• Chemical Name: fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV)
• CAS No.: 950768-01-1
• Molecular Formula: C₃₃H₃₄OP₂Pt
• Molecular Weight: 703.66
• Mol file: 950768-01-1.mol

Synonyms:fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV)

Chemical Property of fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV)

There total 2 articles about fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

fac-(o-bis(diphenylphosphino)benzene)trimethyl(trifluoroacetato)platinum(IV) (1093075-71-8) + potassium hydroxide → fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV) (950768-01-1)

Guidance literature:

With KH; In toluene; under N2; mixt. of Pt complex, toluene and KOH heated to 35°C for2 d; cooled; excess KH added; stirred at ambient temp. for 1 h; filtered; filtrate reduced in vol. in vac.; crystd.; crystals collected;solvent reduced from mother liquor under vac. (second crop); elem. anal .;

DOI:10.1021/om800905q

Reference yield:

fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV) (1093075-66-1) + water (7732-18-5) → (o-bis(diphenylphosphino)benzene)dimethylplatinum(II) + fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV) (950768-01-1) + fac-(o-bis(diphenylphosphino)benzene)PtMe3(OCH2OCH3) (1093075-68-3)

Guidance literature:

In benzene-d6; under N2; H2O (ca. 2 equiv.) added to soln. of Pt complex in C6D6; reacted at ambient temp. over 3 d; equil. react.; not isolated; monitored by (1)H and (31)P NMR spectra;

DOI:10.1021/om800905q

Reference yield: 65.0%

fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV) (950768-01-1) + (4-n-butylbenzene)sulfonamide (1135-00-8) → fac-(o-bis(diphenylphosphino)benzene)PtMe3(NHSO2-p-C6H4(CH2)3CH3) (950767-98-3)

Guidance literature:

In tetrahydrofuran; (under N2); Pt-complex and ligand dissolved in THF, stirred overnight, MgSO4 added, stirred for 10 min; filtered, solvent removed under vac., residue washed with cold Et2O, ppt. dried under vac. overnight, recrystd. from THF/pentane;

DOI:10.1021/ja069191h

upstream raw materials:

fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV)

water

fac-(o-bis(diphenylphosphino)benzene)trimethyl(trifluoroacetato)platinum(IV)

Downstream raw materials:

fac-(o-bis(diphenylphosphino)benzene)PtMe₃(NHSO₂CH₃)

fac-(o-bis(diphenylphosphino)benzene)PtMe₃(NHSO₂-p-C₆H₄(CH₂)3CH₃)

fac-(o-bis(diphenylphosphino)benzene)PtMe₃(NHSO₂-p-C₆H₄CH₃)

fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV)