fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV)

Base Information

• Chemical Name: fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV)
• CAS No.: 1093075-66-1
• Molecular Formula: C₃₄H₃₆OP₂Pt
• Molecular Weight: 717.687
• Mol file: 1093075-66-1.mol

Synonyms:fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV)

Chemical Property of fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV)

There total 2 articles about fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

methanol (67-56-1) + fac-(o-bis(diphenylphosphino)benzene)(acetato)trimethylplatinum(IV) (335630-49-4) → fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV) (1093075-66-1)

Guidance literature:

With potassium; In methanol; toluene; under N2; K pieces and MeOH added to toluene; stirred for 1 d; K removed; Pt complex added; stirred for 5 d; filtered; solvent removed under vac.; recrystd. from toluene layered with pentane; elem. anal.;

DOI:10.1021/om800905q

Reference yield:

methanol (67-56-1) + fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV) (950768-01-1) → (o-bis(diphenylphosphino)benzene)dimethylplatinum(II) + fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV) (1093075-66-1)

Guidance literature:

In tetrahydrofuran-d8; under N2; Pt complex reacted with MeOH in THF-d8 at ambient temp. for 10min; equil. react.; not isolated; monitored by (31)P NMR spectra;

DOI:10.1021/om800905q

Reference yield:

fac-(o-bis(diphenylphosphino)benzene)(methoxo)trimethylplatinum(IV) (1093075-66-1) → (o-bis(diphenylphosphino)benzene)dimethylplatinum(II) + (o-bis(diphenylphosphino)benzene)(methoxo)methylplatinum(II) (1093075-70-7)

Guidance literature:

In benzene-d6; toluene; byproducts: CH3OCHO, (CH3O)2CO, methanol; under N2; in NMR tube; C6D6 added to Pt complex; toluene added; sealed; heated at 100°C for 33-35 d; not isolated; monitored by (1)H and (31)P NMR spectra;

DOI:10.1021/om800905q

upstream raw materials:

methanol

fac-(o-bis(diphenylphosphino)benzene)(acetato)trimethylplatinum(IV)

fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV)

Downstream raw materials:

fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV)

fac-(o-bis(diphenylphosphino)benzene)PtMe₃(OCH₂OCH₃)

(o-bis(diphenylphosphino)benzene)(methoxo)methylplatinum(II)

fac-(o-bis(diphenylphosphino)benzene)(methoxo-d3)trimethylplatinum(IV)