5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine

Base Information

• Chemical Name: 5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine
• CAS No.: 34690-41-0
• Molecular Formula: C₅₄H₃₈N₆Ru
• Molecular Weight: 872.006
• Mol file: 34690-41-0.mol

Synonyms:5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine

Chemical Property of 5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine

There total 6 articles about 5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

pyridine (110-86-1) + Ru(II)(5,10,15,20-tetraphenylporphyrinato)(CO)(pyridine) (41751-82-0) → 5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine (34690-41-0)

Guidance literature:

In pyridine; Irradiation (UV/VIS); photolyzing the Ru complex in a sealed degassed or argon-bubbled pyridine soln.;

DOI:10.1021/j100314a026

Reference yield: 78.0%

pyridine (110-86-1) + Ru(meso-tetrakis-5,10,15,20-phenylporphyrinato)(CH(CO2-2,6-di-tert-butyl-4-methylphenyl))(THF) → 5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine (34690-41-0)

Guidance literature:

In dichloromethane; (under Ar); pyridine added to soln. of Ru-complex in CH2Cl2; silica gel column chromy. CH2Cl2/pentane 1:4;

DOI:10.1021/om800289v

Reference yield:

trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI) (123051-66-1) + Fe(C16H14N2O2)C5H5N (24323-09-9) → (μ-oxo)bis[(1,2-ethanediamino-N,N'-bis(salicylidene))iron(III)] (18601-34-8) + 5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine (34690-41-0)

Guidance literature:

In toluene; N2-atmosphere; 1 h (pptn.); filtration off of Fe-complex, cooling to 0°C, pentane addn. (pptn. of Ru-complex);

DOI:10.1021/ic00120a017

upstream raw materials:

trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI)

Fe(C₁₆H₁₄N₂O₂)C₅H₅N

pyridine

Ru(II)(5,10,15,20-tetraphenylporphyrinato)(CO)(pyridine)

Downstream raw materials:

bis(tetraphenylporphyrinato)ruthenium (II)