trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI)

Base Information

• Chemical Name: trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI)
• CAS No.: 123051-66-1
• Molecular Formula: C₄₄H₂₈N₄O₂Ru
• Molecular Weight: 745.802
• Mol file: 123051-66-1.mol

Synonyms:trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI)

Chemical Property of trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI)

There total 4 articles about trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

Ru(II)(5,10,15,20-tetraphenylporphyrinato)(CO)(MeOH) (89555-37-3) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI) (123051-66-1)

Guidance literature:

In ethanol; dichloromethane; soln. m-CPBA in EtOH was added to soln. (Ru(TPP)(CH3OH)(CO)) in CH2Cl2-EtOH (1:1) and stirred for 1 h; ppt. was filtered, washed with EtOH and dried in vacuo; elem. anal.;

DOI:10.1021/ic048587w

Reference yield:

dichloro(5,10,15,20-tetraphenylporphyrinato)ruthenium(IV) (136676-46-5) → trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI) (123051-66-1)

Guidance literature:

Multi-step reaction with 2 steps

1: silver(I) chlorate / acetonitrile / Anaerobic conditions

2: acetonitrile / 0.75 h / 20 °C / Anaerobic conditions; Visible light

With silver(I) chlorate; In acetonitrile;

DOI:10.1016/j.ica.2011.06.002

Reference yield:

carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II) (32073-84-0) → trans-dioxo(5,10,15,20-tetraphenylporphyrinato)ruthenium(VI) (123051-66-1)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In ethanol; for 1h;

DOI:10.1016/j.jinorgbio.2011.08.003

upstream raw materials:

Ru(II)(5,10,15,20-tetraphenylporphyrinato)(CO)(MeOH)

3-chloro-benzenecarboperoxoic acid

dichloro(5,10,15,20-tetraphenylporphyrinato)ruthenium(IV)

carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II)

Downstream raw materials:

(μ-oxo)bis[(1,2-ethanediamino-N,N'-bis(salicylidene))iron(III)]

5,10,15,20-tetraphenyl-21H,23H-porphyrin-ruthenium(II)-dipyridine

{(meso-tetraphenylporphyrin)bis(tert-butylamine)ruthenium(II)}

(meso-tetraphenylporphyrinato)bis(tetrahydrofuran)ruthenium(II)