p-chlorophenyl perfluorobutyl sulfide

Base Information

• Chemical Name: p-chlorophenyl perfluorobutyl sulfide
• CAS No.: 76665-93-5
• Molecular Formula: C₁₀H₄ClF₉S
• Molecular Weight: 362.646
• Mol file: 76665-93-5.mol

Synonyms:p-chlorophenyl perfluorobutyl sulfide

Chemical Property of p-chlorophenyl perfluorobutyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-chlorophenyl perfluorobutyl sulfide

There total 2 articles about p-chlorophenyl perfluorobutyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane (423-39-2) + p-Chlorothiophenol (106-54-7) → p-chlorophenyl perfluorobutyl sulfide (76665-93-5)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; 1.) r.t., 2 h, 2.) r.t., overnight;

DOI:10.1016/0022-1139(95)03261-B

Reference yield:

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane (423-39-2) + 4-chlorophenyl thiocyanate (3226-37-7) → p-chlorophenyl perfluorobutyl sulfide (76665-93-5)

Guidance literature:

With ethyl bromide; magnesium; Yield given. Multistep reaction; 1.) diethyl ether, -40 deg C, 2.) -15 deg C;

DOI:10.1021/jo00322a047

Reference yield: 87.0%

p-chlorophenyl perfluorobutyl sulfide (76665-93-5) → 4-(Perfluorobutylsulfonyl)chlorobenzene

Guidance literature:

With chromium(VI) oxide; In acetic acid; for 24h; Heating;

DOI:10.1016/0022-1139(95)03261-B

upstream raw materials:

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

4-chlorophenyl thiocyanate

p-Chlorothiophenol

Refernces

• 1、 Nguyen, Thoai,Rubinstein, Michel,Wakselman, Claude. "Reaction of Perfluoroalkyl Carbanions with Thiocyanates. Synthesis of Fluorinated Sulfides and Sulfenyl Chlorides". . p. 1938 - 1940. Retrieved 2007/10/02.