6-(1-(4-iodophenyl)vinyl)-1,1,4,4,7-pentamethyl-1,2,3,4-tetrahydronaphthalene

Base Information

Chemical Name:6-(1-(4-iodophenyl)vinyl)-1,1,4,4,7-pentamethyl-1,2,3,4-tetrahydronaphthalene
CAS No.:926038-66-6
Molecular Formula:C₂₃H₂₇I
Molecular Weight:430.372
Hs Code.:

Synonyms:6-(1-(4-iodophenyl)vinyl)-1,1,4,4,7-pentamethyl-1,2,3,4-tetrahydronaphthalene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 6-(1-(4-iodophenyl)vinyl)-1,1,4,4,7-pentamethyl-1,2,3,4-tetrahydronaphthalene

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Technology Process of 6-(1-(4-iodophenyl)vinyl)-1,1,4,4,7-pentamethyl-1,2,3,4-tetrahydronaphthalene

There total 3 articles about 6-(1-(4-iodophenyl)vinyl)-1,1,4,4,7-pentamethyl-1,2,3,4-tetrahydronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 926038-65-5
2-(4-iodophenyl)-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-methanone

: 676-58-4
methylmagnesium chloride

: 926038-66-6
6-(1-(4-iodophenyl)vinyl)-1,1,4,4,7-pentamethyl-1,2,3,4-tetrahydronaphthalene

Guidance literature:: 2-(4-iodophenyl)-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-methanone; methylmagnesium chloride; In tetrahydrofuran; at -78 - 20 ℃; for 0.166667h; Heating / reflux;

With toluene-4-sulfonic acid; In toluene; for 1h; Heating / reflux;

Reference yield: 79.0%

: 153559-98-9
4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)vinyl)benzoyl chloride

: 926038-66-6
6-(1-(4-iodophenyl)vinyl)-1,1,4,4,7-pentamethyl-1,2,3,4-tetrahydronaphthalene

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In toluene; at 125 ℃; for 12h;
DOI:10.1038/s41557-018-0078-8

Reference yield:

: 926038-65-5
2-(4-iodophenyl)-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-methanone

: triphenylphosphine methyl bromide

: 926038-66-6
6-(1-(4-iodophenyl)vinyl)-1,1,4,4,7-pentamethyl-1,2,3,4-tetrahydronaphthalene

Guidance literature:: triphenylphosphine methyl bromide; With lithium hexamethyldisilazane; In toluene; at -78 ℃; for 0.25h; Cooling with ice;

2-(4-iodophenyl)-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-methanone; In toluene; at -78 ℃;
DOI:10.1021/ml500065q