5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one

Base Information

Chemical Name:5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one
CAS No.:447408-46-0
Molecular Formula:C₃₄H₃₇NO₄SSeSi
Molecular Weight:662.784
Hs Code.:

5-(<i>tert</i>-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one

Synonyms:5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one

Suppliers and Price of 5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

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Technology Process of 5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one

There total 5 articles about 5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 5707-04-0
Phenylselenyl chloride

: 447408-27-7
5-(tert-butyl-diphenyl-silanyloxy)-1-(toluene-4-sulfonyl)-piperidin-2-one

: 447408-46-0
5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; at -50 ℃;
DOI:10.1002/1521-3773(20020503)41:9<1581::AID-ANIE1581>3.0.CO;2-F

Reference yield:

: 102774-92-5
(R)-(+)-5-Hydroxy-2-oxopiperidine

: 447408-46-0
5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / imidazole / dimethylformamide / 20 °C

2: 84 percent / n-BuLi; 4-dimethylaminopyridine / tetrahydrofuran / 0 - 20 °C

3: 65 percent / lithium diisopropylamide / tetrahydrofuran / -50 °C

With 1H-imidazole; dmap; n-butyllithium; lithium diisopropyl amide; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1002/1521-3773(20020503)41:9<1581::AID-ANIE1581>3.0.CO;2-F

Reference yield:

: 98-59-9
p-toluenesulfonyl chloride

: 447408-46-0
5-(tert-butyl-diphenyl-silanyloxy)-3-phenylselanyl-1-(toluene-4-sulfonyl)-piperidin-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / n-BuLi; 4-dimethylaminopyridine / tetrahydrofuran / 0 - 20 °C

2: 65 percent / lithium diisopropylamide / tetrahydrofuran / -50 °C

With dmap; n-butyllithium; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1002/1521-3773(20020503)41:9<1581::AID-ANIE1581>3.0.CO;2-F