5-(1,1-dibutyl-1-stannapentyl)-1-[(3,3-dimethyl-3-silabutoxy)methyl]-2-(phenylsulfonyl)imidazole

Base Information

• Chemical Name: 5-(1,1-dibutyl-1-stannapentyl)-1-[(3,3-dimethyl-3-silabutoxy)methyl]-2-(phenylsulfonyl)imidazole
• CAS No.: 307304-81-0
• Molecular Formula: C₂₇H₄₈N₂O₃SSiSn
• Molecular Weight: 627.551
• Mol file: 307304-81-0.mol

Synonyms:5-(1,1-dibutyl-1-stannapentyl)-1-[(3,3-dimethyl-3-silabutoxy)methyl]-2-(phenylsulfonyl)imidazole

Chemical Property of 5-(1,1-dibutyl-1-stannapentyl)-1-[(3,3-dimethyl-3-silabutoxy)methyl]-2-(phenylsulfonyl)imidazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-(1,1-dibutyl-1-stannapentyl)-1-[(3,3-dimethyl-3-silabutoxy)methyl]-2-(phenylsulfonyl)imidazole

There total 1 articles about 5-(1,1-dibutyl-1-stannapentyl)-1-[(3,3-dimethyl-3-silabutoxy)methyl]-2-(phenylsulfonyl)imidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

tributyltin chloride (1461-22-9) + 2-Benzenesulfonyl-1-(2-trimethylsilanyl-ethoxymethyl)-1H-imidazole (199010-63-4) → 5-(1,1-dibutyl-1-stannapentyl)-1-[(3,3-dimethyl-3-silabutoxy)methyl]-2-(phenylsulfonyl)imidazole (307304-81-0)

Guidance literature:

2-Benzenesulfonyl-1-(2-trimethylsilanyl-ethoxymethyl)-1H-imidazole; With n-butyllithium; In tetrahydrofuran; hexanes; at -78 ℃; for 0.5h;

tributyltin chloride; In tetrahydrofuran; hexanes; at 20 ℃; for 4h;

Reference yield: 87.0%

6-bromo-isoquinoline (34784-05-9) + 5-(1,1-dibutyl-1-stannapentyl)-1-[(3,3-dimethyl-3-silabutoxy)methyl]-2-(phenylsulfonyl)imidazole (307304-81-0) → 1-[(3,3-dimethyl-3-silabutoxy)methyl]-5-(6-isoquinolyl)-2-(phenylsulfonyl)imidazole (1015068-52-6)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(II) oxide; In N,N-dimethyl-formamide; at 100 - 105 ℃; for 8.08333h;

upstream raw materials:

tributyltin chloride

2-Benzenesulfonyl-1-(2-trimethylsilanyl-ethoxymethyl)-1H-imidazole

Downstream raw materials:

1-[(3,3-dimethyl-3-silabutoxy)methyl]-5-(6-isoquinolyl)-2-(phenylsulfonyl)imidazole