formic acid 4-(tert-butyldimethylsilanyloxy)-3-chloro-5-methoxyphenyl ester

Base Information

Chemical Name:formic acid 4-(tert-butyldimethylsilanyloxy)-3-chloro-5-methoxyphenyl ester
CAS No.:1380401-60-4
Molecular Formula:C₁₄H₂₁ClO₄Si
Molecular Weight:316.857
Hs Code.:

Synonyms:formic acid 4-(tert-butyldimethylsilanyloxy)-3-chloro-5-methoxyphenyl ester

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Chemical Property of formic acid 4-(tert-butyldimethylsilanyloxy)-3-chloro-5-methoxyphenyl ester

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Technology Process of formic acid 4-(tert-butyldimethylsilanyloxy)-3-chloro-5-methoxyphenyl ester

There total 3 articles about formic acid 4-(tert-butyldimethylsilanyloxy)-3-chloro-5-methoxyphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 138076-70-7
3-chloro-4-(tert-butyldimethylsilanyloxy)-5-methoxybenzaldehyde

: 1380401-60-4
formic acid 4-(tert-butyldimethylsilanyloxy)-3-chloro-5-methoxyphenyl ester

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 8h; Inert atmosphere; Reflux;
DOI:10.1016/j.bmc.2012.01.021

Reference yield:

: 19463-48-0
5-chlorovanillin

: 1380401-60-4
formic acid 4-(tert-butyldimethylsilanyloxy)-3-chloro-5-methoxyphenyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: dmap; triethylamine / dichloromethane / 8 h / 0 - 25 °C / Inert atmosphere

2: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 8 h / Inert atmosphere; Reflux

With dmap; triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; 2: Baeyer-Villiger oxidation;
DOI:10.1016/j.bmc.2012.01.021

Reference yield:

: 121-33-5,8014-42-4
vanillin

: 1380401-60-4
formic acid 4-(tert-butyldimethylsilanyloxy)-3-chloro-5-methoxyphenyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride; N-chloro-succinimide / tetrahydrofuran / 16 h / 20 °C

2: dmap; triethylamine / dichloromethane / 5 h / 20 °C

3: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 16 h / 20 °C

With dmap; N-chloro-succinimide; sodium hydride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; 3: |Baeyer-Villiger Ketone Oxidation;
DOI:10.1016/j.ejmech.2013.07.042