NONABROMODIPHENYLETHER

Base Information

• Chemical Name: NONABROMODIPHENYLETHER
• CAS No.: 63387-28-0
• Molecular Formula: C12H Br9 O
• Molecular Weight: 880.275
• Hs Code.: 2909309090
• Mol file: 63387-28-0.mol

Synonyms:Benzene,pentabromo(2,3,4,5-tetrabromophenoxy)- (9CI);2,2',3,3',4,4',5,5',6-Nonobromodiphenyl ether; BDE 206; PBDE 206

Chemical Property of NONABROMODIPHENYLETHER

Chemical Property:

• Flash Point: -12oC
• PSA: 9.23000
• LogP: 10.34140
• Storage Temp.: 2-8°C

Purity/Quality:

1,2,3,4,5-Pentabromo-6-(2,3,4,5-tetrabromophenoxy)benzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xn,N
• Hazard Codes: F,Xn,N
• Statements: 11-38-50/53-65-67
• Safety Statements: 60-61-62-33-29-16-9

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1,2,3,4,5-Pentabromo-6-(2,3,4,5-tetrabromophenoxy)benzene is a polybrominated diphenyl ethers (PBDEs) found as a contaminant in soil.

Technology Process of NONABROMODIPHENYLETHER

There total 6 articles about NONABROMODIPHENYLETHER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphenylether (101-84-8) → nonabromodiphenyl ether (63387-28-0) + 2,2',3,3',4,4',5,5',6,6'-Decabromodiphenyl ether (1163-19-5)

Guidance literature:

diphenylether; With bromine; at 40 ℃;

With bromine; aluminum (III) chloride; at 56.5 - 78.4 ℃; for 3.65 - 4.36667h; under 1385.82 - 1458.22 Torr; Product distribution / selectivity;

Reference yield:

diphenylether (101-84-8) → 2,2',3,3',4,5,5',6,6'-nonabromodiphenyl ether (437701-78-5) + nonabromodiphenyl ether (63387-28-0) + BDE-207 (437701-79-6) + 2,2',3,3',4,4',5,5',6,6'-Decabromodiphenyl ether (1163-19-5)

Guidance literature:

With bromine; aluminum (III) chloride; at 55 - 61 ℃; for 6.25h; Product distribution / selectivity;

Reference yield:

diphenylether (101-84-8) → 2,2',3,3',4,5,5',6,6'-nonabromodiphenyl ether (437701-78-5) + nonabromodiphenyl ether (63387-28-0) + BDE-207 (437701-79-6) + C12Br9ClO (918947-03-2) + C12Br9ClO + C12Br9ClO + 2,2',3,3',4,4',5,5',6,6'-Decabromodiphenyl ether (1163-19-5)

Guidance literature:

With bromine; bromine chloride; aluminum (III) chloride; at 56 ℃; for 0.0666667h; Product distribution / selectivity; Heating / reflux;

upstream raw materials:

diphenylether

2,2',3,3',4,4',5,5',6,6'-Decabromodiphenyl ether

Refernces

• 1、 Li, Lina,Chang, Wei,Wang, Ying,Ji, Hongwei,Chen, Chuncheng,Ma, Wanhong,Zhao, Jincai. "Rapid, photocatalytic, and deep debromination of polybrominated diphenyl ethers on Pd-TiO2: Intermediates and pathways". supporting information. p. 11163 - 11170,8. Retrieved 2015/02/02.
• 2、 Wang, Jun,Kliks, Michael M.,Jun, Soojin,Li, Qing X.. "Residues of polybrominated diphenyl ethers in honeys from different geographic regions". experimental part. p. 3495 - 3501. Retrieved 2011/07/07.