N-[Bis(dimethylamino)phosphorylimino-bis(dimethylamino)-lambda5-phosphanyl]-N-methylmethanamine

Base Information

• Chemical Name: N-[Bis(dimethylamino)phosphorylimino-bis(dimethylamino)-lambda5-phosphanyl]-N-methylmethanamine
• CAS No.: 91241-12-2
• Molecular Formula: C10H30 N6 O P2
• Molecular Weight: 312.335
• European Community (EC) Number: 621-327-0
• DSSTox Substance ID: DTXSID70400159
• Nikkaji Number: J3.432.457C
• Wikidata: Q82203001
• Mol file: 91241-12-2.mol

Synonyms:91241-12-2;N-[Bis(dimethylamino)phosphorylimino-bis(dimethylamino)-lambda5-phosphanyl]-N-methylmethanamine;Phosphorictriamide, N,N,N',N'-tetramethyl-N''-[tris(dimethylamino)phosphoranylidene]-;PDPO;SCHEMBL14883341;DTXSID70400159;1,1,3,3,3-Pentakis(dimethylamino)-1 5,3 5-diphosphazene 1-oxide;AKOS015895012;Bis(dimethylamino)[[tri(dimethylamino)phosphoranylidene]amino]phosphine oxide;1,1,3,3,3-Pentakis(dimethylamino)-1lambda5,3lambda5-diphosphazene 1-oxide, 98%;N,N,N',N'-Tetramethyl-N''-[tris(dimethylamino)phosphoranylidene]phosphoric triamide;N,N,N,N-TETRAMETHYL-N-[TRIS(DIMETHYLAMINO)PHOSPHORANYLIDENE]PHOSPHORICTRIAMIDE

Chemical Property of N-[Bis(dimethylamino)phosphorylimino-bis(dimethylamino)-lambda5-phosphanyl]-N-methylmethanamine

Chemical Property:

• Vapor Pressure: 3.24E-05mmHg at 25°C
• Refractive Index: n20/D 1.495(lit.)
• Boiling Point: 354.9°Cat760mmHg
• Flash Point: 168.4°C
• PSA: 65.25000
• Density: 1.1g/cm³
• LogP: 1.84870
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 6
• Exact Mass: 312.19563360
• Heavy Atom Count: 19
• Complexity: 351

Purity/Quality:

99% ^*data from raw suppliers

1,1,3,3,3-PENTAKIS(DIMETHYLAMINO)-1LAMBDA5,3LAMBDA5-DIPHOSPHAZENE 1-OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34-37
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)P(=NP(=O)(N(C)C)N(C)C)(N(C)C)N(C)C

Technology Process of N-[Bis(dimethylamino)phosphorylimino-bis(dimethylamino)-lambda5-phosphanyl]-N-methylmethanamine

There total 2 articles about N-[Bis(dimethylamino)phosphorylimino-bis(dimethylamino)-lambda5-phosphanyl]-N-methylmethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

carbon dioxide (124-38-9,18923-20-1) + 1-ethyl-2,2,4,4,4-pentakis(dimethylamino)-2λ5,4λ5-catenadi(phosphazene) (165535-45-5) → Bis(dimethylamino)<amino>phosphane oxide (91241-12-2) + Tert-butyl isocyanate (1609-86-5)

Guidance literature:

In benzene-d6; at 60 ℃; for 12h; under 760.051 Torr; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1039/c5cc01282a

Reference yield: 94.0%

iminotris(dimethylamino)phosphorane (49778-01-0) + N,N,N',N'-Tetramethylphosphorodiamidic chloride (1605-65-8) → Bis(dimethylamino)<amino>phosphane oxide (91241-12-2)

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃; for 90h; Inert atmosphere;

DOI:10.1002/anie.202001419

upstream raw materials:

iminotris(dimethylamino)phosphorane

N,N,N',N'-Tetramethylphosphorodiamidic chloride

carbon dioxide

1-ethyl-2,2,4,4,4-pentakis(dimethylamino)-2λ⁵,4λ⁵-catenadi(phosphazene)