carbonic acid (Z)-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-vinyl ester cyclohex-2-enyl ester

Base Information

Chemical Name:carbonic acid (Z)-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-vinyl ester cyclohex-2-enyl ester
CAS No.:925462-20-0
Molecular Formula:C₂₁H₃₀O₄Si
Molecular Weight:374.552
Hs Code.:

Synonyms:carbonic acid (Z)-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-vinyl ester cyclohex-2-enyl ester

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Chemical Property of carbonic acid (Z)-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-vinyl ester cyclohex-2-enyl ester

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Technology Process of carbonic acid (Z)-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-vinyl ester cyclohex-2-enyl ester

There total 3 articles about carbonic acid (Z)-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-vinyl ester cyclohex-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 103548-04-5
2-(tert-butyldimethylsilanyloxy)-1-phenylethan-1-one

: 141037-04-9
cyclohex-2-en-1-yl 1H-imidazole-1-carboxylate

: 925462-20-0
carbonic acid (Z)-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-vinyl ester cyclohex-2-enyl ester

: 925462-21-1
carbonic acid (Z)-2-(tert-butyldimethylsilanyloxy)-1-phenyl-vinyl ester cyclohex-2-enyl ester

Guidance literature:: 2-(tert-butyldimethylsilanyloxy)-1-phenylethan-1-one; With sodium hexamethyldisilazane; In 1,2-dimethoxyethane; at -78 ℃; for 0.5h;

cyclohex-2-en-1-yl 1H-imidazole-1-carboxylate; With boron trifluoride diethyl etherate; In 1,2-dimethoxyethane; at -78 ℃; for 0.5h; Further stages.;
DOI:10.1021/jo7016313

Reference yield:

: 66324-10-5
tert-butyldimethyl(1-phenylvinyloxy)silane

: 141036-93-3
chloroformiate de 1-cyclohexenyle

: 925462-20-0
carbonic acid (Z)-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-vinyl ester cyclohex-2-enyl ester

: 925462-21-1
carbonic acid (Z)-2-(tert-butyldimethylsilanyloxy)-1-phenyl-vinyl ester cyclohex-2-enyl ester

Guidance literature:: tert-butyldimethyl(1-phenylvinyloxy)silane; With N,N,N,N,-tetramethylethylenediamine; sodium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 1h;

chloroformiate de 1-cyclohexenyle; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1021/ja067342a

Reference yield:

: 822-67-3
Cyclohex-2-enol

: 925462-20-0
carbonic acid (Z)-2-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-vinyl ester cyclohex-2-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: toluene; tetrahydrofuran / 0.83 h / cooling

2.1: sodium hexamethyldisilazane; tetramethylethylenediamine / tetrahydrofuran / 1 h / -78 °C

2.2: 580 mg / tetrahydrofuran / -78 - 20 °C

With N,N,N,N,-tetramethylethylenediamine; sodium hexamethyldisilazane; In tetrahydrofuran; toluene;
DOI:10.1021/ja067342a