(S)-(+)-2-Amino-3-methylbutane

Base Information

Chemical Name:(S)-(+)-2-Amino-3-methylbutane
CAS No.:22526-46-1
Molecular Formula:C5H13N
Molecular Weight:87.1649
Hs Code.:2921199090
European Community (EC) Number:627-253-5
UNII:32QJA2ZJ2A
DSSTox Substance ID:DTXSID80426446
Nikkaji Number:J60.644H
Wikidata:Q27256184
Mol file:22526-46-1.mol

Synonyms:22526-46-1;(S)-(+)-2-Amino-3-methylbutane;(2S)-3-methylbutan-2-amine;(S)-(+)-3-Methyl-2-butylamine;(S)-3-methyl-2-butylamine;2-Butanamine, 3-methyl-, (2S)-;(S)-3-Methylbutane-2-amine;32QJA2ZJ2A;(s)-2-amino-3-methylbutane;1,2-Dimethylpropylamine, (S)-;3-Methyl-2-butylamine, (2S)-;Propylamine, 1,2-dimethyl-, (S)-;UNII-32QJA2ZJ2A;(S)-3-methylbutan-2-amine;(S)-1,2-dimethylpropylamine;J60.644H;MFCD01075732;(2S)-3-methyl-2-butanamine;(1S)-1,2-Dimethylpropylamine;DTXSID80426446;JOZZAIIGWFLONA-YFKPBYRVSA-N;(s)-(+)-3-methyl-2-butyl-amine;AKOS015841166;EN300-89230;A12293;J-014752;(S)-(+)-2-Amino-3-methylbutane, >=98.0% (GC);(S)-(+)-2-Amino-3-methylbutane, 98+%, ee 99%;Q27256184;(S)-(+)-2-Amino-3-methylbutane, ChiPros(R), produced by BASF

Suppliers and Price of (S)-(+)-2-Amino-3-methylbutane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(S)-3-Methyl-2-butanamine
0.5g
$ 265.00

Chemenu
(2S)-3-methylbutan-2-amine 95%+
25g
$ 1380.00

Biosynth Carbosynth
(S)-(+)-2-Amino-3-methylbutane
1 g
$ 85.00

Biosynth Carbosynth
(S)-(+)-2-Amino-3-methylbutane
500 mg
$ 60.00

Biosynth Carbosynth
(S)-(+)-2-Amino-3-methylbutane
250 mg
$ 40.00

Biosynth Carbosynth
(S)-(+)-2-Amino-3-methylbutane
2 g
$ 144.00

Biosynth Carbosynth
(S)-(+)-2-Amino-3-methylbutane
5 g
$ 300.00

American Custom Chemicals Corporation
(S)-(+)-3-METHYL-2-BUTYLAMINE 95.00%
5G
$ 939.28

American Custom Chemicals Corporation
(S)-(+)-3-METHYL-2-BUTYLAMINE 95.00%
1G
$ 644.82

AK Scientific
(S)-(+)-2-Amino-3-methylbutane
500mg
$ 131.00

Total 20 raw suppliers

Chemical Property of (S)-(+)-2-Amino-3-methylbutane

Chemical Property:

Vapor Pressure:69.2mmHg at 25°C
Refractive Index:n20/D 1.405
Boiling Point:85.5 °C at 760 mmHg
PKA:10.80±0.10(Predicted)
Flash Point:< 21 °C
PSA：26.02000
Density:0.754 g/cm³
LogP:1.68990
Sensitive.:Air Sensitive
XLogP3:1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:87.104799419
Heavy Atom Count:6
Complexity:32.9

Purity/Quality:

98%,99%, ^*data from raw suppliers

(S)-3-Methyl-2-butanamine ^*data from reagent suppliers

Safty Information:

Pictogram(s): FC
Hazard Codes:F,C,N
Statements: 11-20/21/22-35-51/53-34
Safety Statements: 26-36/37/39-45-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C(C)N
Isomeric SMILES:C[C@@H](C(C)C)N
Uses (S)-3-Methyl-2-butanamine is a chiral reagent used in the study of enantioselective recognition of amines.

Technology Process of (S)-(+)-2-Amino-3-methylbutane

There total 26 articles about (S)-(+)-2-Amino-3-methylbutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.6%

: 563-80-4
3-methyl-butan-2-one

: 2550-26-7
4-Phenyl-2-butanone

: 598-74-3,22526-46-1,34701-33-2,110509-11-0
(2R)-3-methyl-2-butylamine

: 937-52-0,22148-77-2,1199266-89-1
(R)-1-methyl-3-phenylpropylamine

Guidance literature:: With Candida boidinii formate dehydrogenase; pyridoxal 5'-phosphate; Aspergillus terreus ω-trans aminase; Lysinibacillus fusiformis leucine dehydrogenase; ammonium formate; nicotinamide adenine dinucleotide; In aq. buffer; at 30 ℃; for 24h; pH=8.8; Catalytic behavior; Green chemistry; Enzymatic reaction;
DOI:10.1021/acs.joc.9b02445

Reference yield:

: 4276-09-9,473-75-6
(R)-2-amino-3-methylbutanol

: 22526-46-1
(2S)-3-methylbutan-2-amine

Guidance literature:: Multi-step reaction with 4 steps

1: 99 percent / CHCl₃ / 0 - 20 °C

2: 84 percent / iodine; triphenylphosphine polystyryl-supported; imidazole / CH₂Cl₂ / 2 h / Heating

3: 91 percent / N-Selectride / tetrahydrofuran / 1.5 h / 5 °C

4: 92 percent / trifluoroacetic acid / CH₂Cl₂ / 18 h / 20 °C

With 1H-imidazole; triphenylphosphine polystyryl-supported; iodine; sodium tri-sec-butylborohydride; trifluoroacetic acid; In tetrahydrofuran; dichloromethane; chloroform; 1: Substitution / 2: Substitution / 3: Reduction / 4: Hydrolysis;
DOI:10.1021/jo000242h