(η-cyclopentadienyl)Ir(triphenylphosphine)H2

Base Information

• Chemical Name: (η-cyclopentadienyl)Ir(triphenylphosphine)H2
• CAS No.: 113161-56-1
• Molecular Formula: C₂₃H₂₂IrP
• Molecular Weight: 521.621
• Mol file: 113161-56-1.mol

Synonyms:(η-cyclopentadienyl)Ir(triphenylphosphine)H2

Chemical Property of (η-cyclopentadienyl)Ir(triphenylphosphine)H2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (η-cyclopentadienyl)Ir(triphenylphosphine)H2

There total 1 articles about (η-cyclopentadienyl)Ir(triphenylphosphine)H2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(η-cyclopentadienyl)Ir(triphenylphosphine)I2 → (η-cyclopentadienyl)Ir(triphenylphosphine)H2 (113161-56-1)

Guidance literature:

With Zn; acetic acid; NaCl; In methanol; water; under N2 or Ar; Schlenk flask charged with Ir-complex, abs. MeOH, Zn, glacial acetic acid added, stirred 2h, color change from red slurry to yellow soln., satd. aq. NaCl soln. added; extn. (toluene), combined extracts evapn. (vac.), recrystn. (CH2Cl2:Et2O = 20:80);

DOI:10.1021/ja00159a001

Reference yield: 81.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + (η-cyclopentadienyl)Ir(triphenylphosphine)H2 (113161-56-1) → {(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4 (113161-54-9)

Guidance literature:

In dichloromethane; under N2 or Ar; Schlenk flask charged with Ir-complex and CH2Cl2, cooled to 0°C, HBF4*Et2O added dropwise, stirred 10min; solvent vol. reduced (vac., ca 50%), pptn. with Et2O, washed (Et2O), recrystn. (concd. CH2Cl2 soln.), elem. anal.;

DOI:10.1021/ja00159a001

Reference yield:

(η-cyclopentadienyl)Ir(triphenylphosphine)H2 (113161-56-1) + deuterium (16873-17-9,12184-84-8) → (η-cyclopentadienyl)Ir(triphenylphosphine)D2

Guidance literature:

In not given; byproducts: H2; D2 (20psi); analogous Shapley, J.R., Adair, P.C., Lawson, R.J. Inorg.Chem. 1982, 21, 1702-1704; Adair, P.C. Ph.D. Thesis, University of Illinois (Urbana-Champaign), 1980;

DOI:10.1021/ja00159a001

Downstream raw materials:

{(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4