{(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4

Base Information

• Chemical Name: {(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4
• CAS No.: 113161-54-9
• Molecular Formula: BF₄*C₂₃H₂₃IrP
• Molecular Weight: 609.434
• Mol file: 113161-54-9.mol

Synonyms:{(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4

Chemical Property of {(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of {(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4

There total 1 articles about {(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + (η-cyclopentadienyl)Ir(triphenylphosphine)H2 (113161-56-1) → {(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4 (113161-54-9)

Guidance literature:

In dichloromethane; under N2 or Ar; Schlenk flask charged with Ir-complex and CH2Cl2, cooled to 0°C, HBF4*Et2O added dropwise, stirred 10min; solvent vol. reduced (vac., ca 50%), pptn. with Et2O, washed (Et2O), recrystn. (concd. CH2Cl2 soln.), elem. anal.;

DOI:10.1021/ja00159a001

Reference yield:

{(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4 (113161-54-9) + deuterium (16873-17-9,12184-84-8) → {(η-cyclopentadienyl)Ir(triphenylphosphine)D3}BF4

Guidance literature:

In dichloromethane; byproducts: H2; under Ar or N2; in a NMR tube fitted with a Kontes high vac. stopcock placed Ir-complex, CH2Cl2 transferred into the tube, followed by freeze-pump-thaw cycles, pressurized to 30psi with D2, light excluded, react. time 18h; not isolated, detected by NMR;

DOI:10.1021/ja00159a001

Reference yield:

{(η-cyclopentadienyl)Ir(triphenylphosphine)H3}BF4 (113161-54-9) + carbon monoxide (201230-82-2) → ((η-cyclopentadienyl)Ir(triphenylphosphine)(CO)H)BF4

Guidance literature:

In dichloromethane; byproducts: H2; under Ar or N2; Pyrex bomb charged with Ir-complex and CH2Cl2 (vac. transfer), subjected to freeze-pump-thaw cycles, charged with 40psi CO (gas), react. time 1h; not isolated, detected by IR;

DOI:10.1021/ja00159a001

upstream raw materials:

tetrafluoroboric acid diethyl ether

(η-cyclopentadienyl)Ir(triphenylphosphine)H2