10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)

Base Information

• Chemical Name: 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)
• CAS No.: 1246450-05-4
• Molecular Formula: C₆₄H₆₀N₄Zn
• Molecular Weight: 950.597
• Mol file: 1246450-05-4.mol

Synonyms:10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)

Chemical Property of 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

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Useful:

Technology Process of 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)

There total 3 articles about 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

5,15-bis(3,5-di-tert-butylphenyl)porphyrin ZnII (187387-14-0) + 1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene (349666-24-6) → 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) (1246450-05-4) + 10,20-bis(3,5-di-tert-butylphenyl)-5,15-bis-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) (1246450-10-1)

Guidance literature:

5,15-bis(3,5-di-tert-butylphenyl)porphyrin Zn^II; With pyridine; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane; at -10 - 0 ℃; for 0.25h; Reflux; Inert atmosphere;

1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene; With pyridine; caesium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; for 12h; Reflux; Inert atmosphere;

Reference yield: 62.0%

[5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II) (215313-78-3) + (5-bromo-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) (294183-84-9) + 1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene (349666-24-6) → 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) (1246450-05-4) + 10,20-bis(3,5-di-tert-butylphenyl)-5,15-bis-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) (1246450-10-1)

Guidance literature:

With caesium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; for 12h; Inert atmosphere; Reflux;

Reference yield: 62.0%

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (187387-14-0) + 1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene (349666-24-6) → [10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato-(2-κN21,κN22,κN23,κN24)]zinc(II) (1246450-05-4) + [10,20-bis(3,5-di-tert-butylphenyl)-5,15-bis(1-pyrenyl)porphyrinato-(2-κN21,κN22,κN23,κN24)]zinc(II) (1246450-10-1)

Guidance literature:

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II); With N-Bromosuccinimide; sodium chloride; In pyridine; dichloromethane; at -10 - 0 ℃; Inert atmosphere;

1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In toluene; at 110 ℃; for 12h; Inert atmosphere;

DOI:10.1002/anie.201002669

upstream raw materials:

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene

[5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II)

(5-bromo-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Downstream raw materials:

{μ-[10,10'-bis(1-pyrenyl)-5,5',15,15'-tetrakis(3,5-di-tert-butylphenyl)-18,18',20,20'-dicyclo-2,2'-biporphyrinato(4-)-KN21,KN22,KN23,KN24,KN21',KN22',KN23',KN24']}dizinc(II)

10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)-10-bromoporphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II)

Refernces

• 1、 -. "VISIBLE/NIR PHOTODETECTORS". Page/Page column 59-60. . Retrieved 2011/04/14.