[Ru^II(η⁶-p-cymene)(PPh₃)(CH₃CN)Cl]PF₆

Base Information

Chemical Name:[Ru^II(η⁶-p-cymene)(PPh₃)(CH₃CN)Cl]PF₆
CAS No.:923276-33-9
Molecular Formula:C₃₀H₃₂ClNPRu*F₆P
Molecular Weight:719.052
Hs Code.:

[Ru<sup>II</sup>(η<sup>6</sup>-p-cymene)(PPh<sub>3</sub>)(CH<sub>3</sub>CN)Cl]PF<sub>6</sub>

Synonyms:[Ru^II(η⁶-p-cymene)(PPh₃)(CH₃CN)Cl]PF₆

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Chemical Property of [Ru^II(η⁶-p-cymene)(PPh₃)(CH₃CN)Cl]PF₆

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Technology Process of [Ru^II(η⁶-p-cymene)(PPh₃)(CH₃CN)Cl]PF₆

There total 1 articles about [Ru^II(η⁶-p-cymene)(PPh₃)(CH₃CN)Cl]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: ammonium hexafluorophosphate

: 52490-94-5
[dichloro(p-cymene)(triphenylphosphane)ruthenium(II)]

: 75-05-8,26809-02-9
acetonitrile

: 923276-33-9
[Ru^II(η⁶-p-cymene)(PPh₃)(CH₃CN)Cl]PF₆

Guidance literature:: In acetonitrile; Sonication; suspn. Ru complex and NH4PF6 in MeCN was heated at reflux for 10 min; solvent was removed, residue was extd. with CH2Cl2 and filtered through Celite, pentane was added, supernatant was removed by decantation, residue was sonicated twice in pentane and Et2O; elem. anal.;
DOI:10.1021/om060752n

Reference yield: 99.0%

: 288-32-4
1H-imidazole

: 923276-33-9
[Ru^II(η⁶-p-cymene)(PPh₃)(CH₃CN)Cl]PF₆

: 1357080-73-9
chlorido(η6-p-cymene)(imidzole)(triphenylphosphine)ruthenium(II) hexafluorophosphate

Guidance literature:: In dichloromethane; Ar; ligand and Ru compd. (1.1:1 molar ratio), mixt. in DCM stirred for 2h at room temp.; concd., pptd. (pentane), filtered off, washed (pentane), dried (vac.), elem. anal.;
DOI:10.1016/j.ica.2011.10.007

Reference yield: 96.0%

: 923276-33-9
[Ru^II(η⁶-p-cymene)(PPh₃)(CH₃CN)Cl]PF₆

: 672-66-2
Dimethyl(phenyl)phosphine

: 936565-91-2
[RuCl(PPhMe2)(PPh3)(η6-p-cymene)]PF6

Guidance literature:: In dichloromethane; under N2 atm. to soln. Ru complex in CH2Cl2 PPhMe2 was added and stirredat room temp. for 30 min; Et2O was added, ppt. was washed with Et2O; elem. anal.;
DOI:10.1021/om070050d