Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Cl

Base Information

Chemical Name:Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Cl
CAS No.:434314-08-6
Molecular Formula:C₆₂H₄₇ClP₃Rh
Molecular Weight:1023.33
Hs Code.:

Synonyms:Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Cl

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Chemical Property of Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Cl

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Technology Process of Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Cl

There total 2 articles about Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: [Rh((S)-BINAP)Cl]₂

: 603-35-0
triphenylphosphine

: 434314-08-6
Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Cl

Guidance literature:: In toluene; soln. of Rh-complex and PPh3 in toluene was stirred at room temp. for 3 h under N2; concd. in vacuo, tritulated in Et2O, supernatant was removed at 0°C, washed with Et2O at 0°C, dried under vac.; elem. anal.;
DOI:10.1021/ja012711i

Reference yield:

: 959928-06-4
2-chloro-1-ethyl-1,2-azaborine

: 881662-42-6,434314-09-7
Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Ph

: 434314-08-6
Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Cl

: 287735-81-3
1-ethyl-1,2-dihydro-2-phenyl-1,2-azaborine

Guidance literature:: In tetrahydrofuran-d8; at 20 ℃; for 1h;
DOI:10.1002/anie.201304443

Reference yield: 73.0%

: 434314-08-6
Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Cl

: 591-51-5
phenyllithium

: 881662-42-6,434314-09-7
Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Ph

Guidance literature:: In diethyl ether; byproducts: LiCl; Rh-complex was suspended in Et2O, PhLi was added at 0°C, stirred at room temp. for 72 h under N2; filtered, solvent was removed in vacuo, dissolved in Et2O, alumina column with Et2O; elem. anal.;
DOI:10.1021/ja012711i