287735-81-3

Upstream product

• 959928-06-4 2-chloro-1-ethyl-1,2-azaborine 
• 934-56-5 trimethyl(phenyl)stannane 
• 881662-42-6 Rh((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(triphenylphosphine)Ph 
• 75-09-2 dichloromethane 
• 287735-79-9 N-allyl-N-ethylaminoallylphenylborane 
• 287735-80-2 1-ethyl-3,6-dihydro-2-phenyl-1,2-azaborine 
• 287735-78-8 N-allyl-N-ethylaminoallylboron chloride 

Relevant academic research and scientific papers

Diversity through isosterism: The case of boron-substituted 1,2-dihydro-1,2-azaborines

(Chemical Equation Presented) The first general synthesis of boron-substituted 1,2-dihydro-1,2-azaborines is described. The versatile 1,2-dihydro-1,2-azaborine precursor 4 is synthesized through a ring-closing metathesis-oxidation sequence. Treatment of 4

1,2-AZABORINE COMPOUNDS AND SYNTHESIS

A compound, or a pharmaceutically acceptable salt or ester thereof, having a structure of formula (I), wherein R1 is a substituted aryl or an optionally-substituted heteroaryl, provided that the heteroaryl is not pyridyl or azaborine; and each

Rhodium-catalyzed boron arylation of 1,2-azaborines

A Sn-phony in B! BN isosteres of biphenyl compounds are prepared through Rh-catalyzed cross-coupling between 2-chloro-1,2-azaborines and arylstannanes (see scheme). The synthetic method should enable investigations of structure-activity relationships (SAR

Synthesis of 1,2-dihydro-1,2-azaborines and their conversion to tricarbonyl chromium and molybdenum complexes

1,2-dihydro-1,2-azaborines (1c, 1d, and 1e) have been prepared by the reaction of the corresponding 2,3-dihydro-1H-1,2-azaborol-3-yllithium reagents (1c, 1d, and 1e). The reaction of 1e with Py3Mo(CO)3 and BF3·OEt2/s

A synthesis of aromatic five- and six-membered B-N heterocycles via ring closing metathesis

equation presented The ring closing metathesis on appropriate vinyl or allyl aminoboranes (1 or 2) gives azaboracycloalkenes (3 or 4) which can be converted to azaborolides (5) or azaborines (6).