(1S,E)-(-)-Camphorquinone 3-oxime

Base Information

Chemical Name:(1S,E)-(-)-Camphorquinone 3-oxime
CAS No.:251645-83-7
Molecular Formula:C₁₀H₁₅NO₂
Molecular Weight:181.235
Hs Code.:2929900090
European Community (EC) Number:636-268-6,803-666-8
Nikkaji Number:J2.481.043G
Mol file:251645-83-7.mol

Synonyms:(1S,E)-(-)-Camphorquinone 3-oxime;251645-83-7;(1S,3Z,4R)-3-hydroxyimino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one;anti-(1S)-(-)-Camphorquinone 3-oxime;BP-13121;J-015845;(1S,4beta)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione 3-[(E)-oxime]

Suppliers and Price of (1S,E)-(-)-Camphorquinone 3-oxime

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
(1S,E)-(?)-Camphorquinone 3-oxime 99%
1g
$ 143.00

Biosynth Carbosynth
(1S,E)-(?)-Camphorquinone 3-oxime
1 g
$ 178.00

Biosynth Carbosynth
(1S,E)-(?)-Camphorquinone 3-oxime
500 mg
$ 100.00

Biosynth Carbosynth
(1S,E)-(?)-Camphorquinone 3-oxime
250 mg
$ 60.00

Biosynth Carbosynth
(1S,E)-(?)-Camphorquinone 3-oxime
2 g
$ 310.00

Biosynth Carbosynth
(1S,E)-(?)-Camphorquinone 3-oxime
5 g
$ 620.00

Apolloscientific
(1S,E)-(?)-Camphorquinone 3-oxime 95%
1g
$ 363.00

American Custom Chemicals Corporation
(1S,E)-(?)-Camphorquinone 3-oxime 95.00%
20G
$ 2090.00

American Custom Chemicals Corporation
(1S,E)-(?)-Camphorquinone 3-oxime 95.00%
2G
$ 852.50

American Custom Chemicals Corporation
(1S,E)-(?)-Camphorquinone 3-oxime 95.00%
1G
$ 249.90

Total 5 raw suppliers

Chemical Property of (1S,E)-(-)-Camphorquinone 3-oxime

Chemical Property:

Vapor Pressure:0.0219mmHg at 25°C
Melting Point:154-156 ºC
Refractive Index:1.515
Boiling Point:276.8°Cat760mmHg
PKA:9.35±0.60(Predicted)
Flash Point:121.2°C
PSA：49.66000
Density:1.25g/cm³
LogP:1.84180
XLogP3:2.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:181.110278721
Heavy Atom Count:13
Complexity:306

Purity/Quality:

99% ^*data from raw suppliers

(1S,E)-(?)-Camphorquinone 3-oxime 99% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 22-43
Safety Statements: 22-24/25-36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2CCC1(C(=O)C2=NO)C)C
Isomeric SMILES:C[C@]12CC[C@H](C1(C)C)/C(=N/O)/C2=O

Technology Process of (1S,E)-(-)-Camphorquinone 3-oxime

There total 3 articles about (1S,E)-(-)-Camphorquinone 3-oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 464-48-2,68546-28-1
(1S)-camphor

: 251645-83-7
3-(hydroxyimino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

Guidance literature:: With isopentyl nitrite;
DOI:10.1016/S0040-4039(01)91142-6

Reference yield:

: 464-49-3,68546-28-1
(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

: 251645-83-7
3-(hydroxyimino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

: 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione 3-oxime

Guidance literature:: (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one; With potassium tert-butylate; In diethyl ether; at -30 - 20 ℃; for 0.5h; Inert atmosphere;

With isopentyl nitrite; In diethyl ether; at -30 - 20 ℃; for 16.3333h; Inert atmosphere;
DOI:10.15227/orgsyn.082.0087