RuHBr(CO)(P(C₆H₅)3)3

Base Information

Chemical Name:RuHBr(CO)(P(C₆H₅)3)3
CAS No.:100678-61-3
Molecular Formula:C₅₅H₄₆BrOP₃Ru
Molecular Weight:996.865
Hs Code.:

RuHBr(CO)(P(C<sub>6</sub>H<sub>5</sub>)3)3

Synonyms:RuHBr(CO)(P(C₆H₅)3)3

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of RuHBr(CO)(P(C₆H₅)3)3

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Technology Process of RuHBr(CO)(P(C₆H₅)3)3

There total 2 articles about RuHBr(CO)(P(C₆H₅)3)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 50661-73-9
hydridoruthenium(carbonylbis(triphenylphosphine)ruthenium(II))(OCOCH₃)

: 100678-61-3
RuHBr(CO)(P(C₆H₅)3)3

Guidance literature:: With HBr; triphenyl phosphine; (C₂H₅)3N; In methanol; toluene; byproducts: CH3COOH, (C2H5)3N*HBr; (N2); HBr added to a suspn. of Ru-complex and refluxed for 1 h; evapd.;toluene, triphenyl phosphine and (C2H5)3N added; refluxed for 2 h; cooled; concentrated; pentane added; filtered; washed with toluene, methanol, water, methanol, and pentane; dried in vacuo; recrystd. from CH2Cl2/heptane; elem. anal.;

Reference yield:

: 201230-82-2
carbon monoxide

: 14014-88-1
ruthenium(III) bromide

: 603-35-0
triphenylphosphine

: 16971-34-9,100678-61-3
RuHBr(CO)[P(C₆H₅)3]3

Guidance literature:: With ethylene glycol; In ethylene glycol; formation from RuBr3 and PPh3 in ethylene glycol at 190°C;;
DOI:10.1021/ja01490a071

Reference yield: 60.0%

: 16971-34-9,100678-61-3
RuHBr(CO)[P(C₆H₅)3]3

: 693-13-0
diisopropyl-carbodiimide

: bromocarbonyl(N-isopropenyl-N'-isopropylformamidinato)bis(triphenylphosphine)ruthenium(II)

Guidance literature:: In benzene; reflux for 6 h; concd. under reduced pressure, diluted with methanol, ppt. washed with methanol and light petroleum, recrystd. from CH2Cl2-CH3OH; elem. anal.;
DOI:10.1039/DT9810001327