50661-73-9

Basic information

• Product Name: hydridoruthenium(carbonylbis(triphenylphosphine)ruthenium(II))(OCOCH₃)
• Synonyms: hydridoruthenium(carbonylbis(triphenylphosphine)ruthenium(II))(OCOCH₃)
• CAS NO: 50661-73-9
• Molecular Weight: 713.715
• Mol File: 50661-73-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: hydridoruthenium(carbonylbis(triphenylphosphine)ruthenium(II))(OCOCH₃)(CAS DataBase Reference)
• NIST Chemistry Reference: hydridoruthenium(carbonylbis(triphenylphosphine)ruthenium(II))(OCOCH₃)(50661-73-9)
• EPA Substance Registry System: hydridoruthenium(carbonylbis(triphenylphosphine)ruthenium(II))(OCOCH₃)(50661-73-9)

Safety Data

• Hazardous Substances Data: 50661-73-9(Hazardous Substances Data)

Upstream product

• 132751-57-6 {hydridobis(acetonitrile)bis(triphenylphosphine)carbonylruthenium(II)}BF₄ 
• 127-09-3 sodium acetate 
• 25360-32-1 carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 64-19-7 acetic acid 

Downstream Products

• 100678-61-3 RuHBr(CO)(P(C₆H₅)3)3 
• 113220-59-0 {(Ph3P)4Ru2(CO)2(μ-H)2(μ-OAc)}{HC(SO2CF3)2} 

Relevant articles and documents

A Selective and Functional Group-Tolerant Ruthenium-Catalyzed Olefin Metathesis/Transfer Hydrogenation Tandem Sequence Using Formic Acid as Hydrogen Source

A ruthenium-catalyzed transfer hydrogenation of olefins utilizing formic acid as a hydrogen donor is described. The application of commercially available alkylidene ruthenium complexes opens access to attractive C(sp3)-C(sp3) bond formation in an olefin metathesis/transfer hydrogenation sequence under tandem catalysis conditions. High chemoselectivity of the developed methodology provides a remarkable synthetic tool for the reduction of various functionalized alkenes under mild reaction conditions. The developed methodology is applied for the formal synthesis of the drugs pentoxyverine and bencyclane.

Insertion reactions of acrylonitrile with hydridocarbonylbis(triphenylphosphine)ruthenium(II) carboxylates

Reactions between and carboxylic acid in 2-methoxyethanol give white crystalline carboxylate complexes of the type , where R = H, CH3, C2H5, C3H7, C6H5, p-OCH3C6H4 or p-CH3C6H4.In these octahedral complexes the carb