3-((di-tert-butylphosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride

Base Information

• Chemical Name: 3-((di-tert-butylphosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride
• CAS No.: 1416953-44-0
• Molecular Formula: C₂₁H₃₄N₂P*Cl
• Molecular Weight: 380.941
• Mol file: 1416953-44-0.mol

Synonyms:3-((di-tert-butylphosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride

Chemical Property of 3-((di-tert-butylphosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-((di-tert-butylphosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride

There total 6 articles about 3-((di-tert-butylphosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

3-((di-tert-butylphosphoryl)methyl)-1-mesityl-1H-imidazol-3-ium 4-methylbenzenesulfonate (1416953-42-8) → 3-((di-tert-butylphosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride (1416953-44-0)

Guidance literature:

With trichlorosilane; In chlorobenzene; at 80 ℃; for 48h; Inert atmosphere;

DOI:10.1021/om300487r

Reference yield: 94.0%

3-((di-tert-butyldichloro-λ4-phosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride → 3-((di-tert-butylphosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride (1416953-44-0)

Guidance literature:

With hexachlorodisilane; In dichloromethane; Glovebox; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.0c00788

Reference yield:

di-tert-butyl(hydroxymethyl)phosphine oxide (131535-19-8) → 3-((di-tert-butylphosphaneyl)methyl)-1-mesityl-1H-imidazol-3-ium chloride (1416953-44-0)

Guidance literature:

Multi-step reaction with 3 steps

1: triethylamine / tetrahydrofuran / 12 h / 20 °C

2: toluene / 168 h / 120 °C / Inert atmosphere

3: trichlorosilane / chlorobenzene / 48 h / 80 °C / Inert atmosphere

With trichlorosilane; triethylamine; In tetrahydrofuran; chlorobenzene; toluene;

DOI:10.1021/om300487r

upstream raw materials:

di-tert-butyl(hydroxymethyl)phosphine oxide

di-tert-butyl(mesitylmethyl)phosphine oxide

3-((di-tert-butylphosphoryl)methyl)-1-mesityl-1H-imidazol-3-ium 4-methylbenzenesulfonate

N-(2,4,6-trimethylphenyl)imidazole

Downstream raw materials:

3-mesityl-1-(di-tert-butylphosphinomethyl)imidazol-2-ylidene