Tris(2-methoxyphenyl)bismuth Dichloride

Base Information

Chemical Name:Tris(2-methoxyphenyl)bismuth Dichloride
CAS No.:121899-81-8
Molecular Formula:C21H21 Bi Cl2 O3
Molecular Weight:601.282
Hs Code.:
European Community (EC) Number:678-254-2
DSSTox Substance ID:DTXSID20442307
Mol file:121899-81-8.mol

Synonyms:Tris(2-methoxyphenyl)bismuth Dichloride;121899-81-8;Dichloro-tris(2-methoxyphenyl)bismuth;Bismuth, dichlorotris(2-methoxyphenyl)-;DTXSID20442307;MFCD04038429;AKOS015851740;Tris(2-methoxyphenyl)bismuthDichloride;AS-64049;DICHLOROTRIS(2-METHOXYPHENYL)BISMUTHANE;T71646;J-004705

Suppliers and Price of Tris(2-methoxyphenyl)bismuth Dichloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
Tris(2-methoxyphenyl)bismuth Dichloride >98.0%(T)
5g
$ 800.00

TCI Chemical
Tris(2-methoxyphenyl)bismuth Dichloride >98.0%(T)
1g
$ 222.00

Chem-Impex
Tris(2-methoxyphenyl)bismuthdichloride,98%(Assaybytitration) 98%(Assaybytitration)
1G
$ 230.72

Chem-Impex
Tris(2-methoxyphenyl)bismuthdichloride,≥98%(Assaybytitration) ≥98%(Assaybytitration)
5G
$ 853.80

American Custom Chemicals Corporation
TRIS(2-METHOXYPHENYL)BISMUTH DICHLORIDE 95.00%
5G
$ 1147.32

American Custom Chemicals Corporation
TRIS(2-METHOXYPHENYL)BISMUTH DICHLORIDE 95.00%
1G
$ 232.05

AK Scientific
Tris(2-methoxyphenyl)bismuth Dichloride
1g
$ 361.00

Total 9 raw suppliers

Chemical Property of Tris(2-methoxyphenyl)bismuth Dichloride

Chemical Property:

Melting Point:183 °C(dec.)
PSA：27.69000
LogP:5.86520
Storage Temp.:Refrigerator
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:600.06717
Heavy Atom Count:27
Complexity:424

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tris(2-methoxyphenyl)bismuth Dichloride >98.0%(T) ^*data from reagent suppliers

Safty Information:

Pictogram(s): R36/37/38:;
Hazard Codes:R36/37/38:;
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=CC=C1[Bi](C2=CC=CC=C2OC)(C3=CC=CC=C3OC)(Cl)Cl

Technology Process of Tris(2-methoxyphenyl)bismuth Dichloride

There total 3 articles about Tris(2-methoxyphenyl)bismuth Dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

: 83724-41-8
tris(2-methoxyphenyl)bismuthine

: 121899-81-8
tris(2-methoxyphenyl)bismuth dichloride

Guidance literature:: With ozone; In dichloromethane; solvent ozonization at -78°C for 1 h, Bi-compd. soln. addn. to ozonized solvent in 1 portion, suspn. allowing to warm to room temp. (30 min), filtration (Celite), filtrate evapn. (reduced pressure); residue chromy. (silica gel, CH2Cl2/EtOH 1:0 to 50:1); elem. anal.;
DOI:10.1039/a700379j

Reference yield:

: 578-57-4
2-bromoanisole

: 121899-81-8
tris(2-methoxyphenyl)bismuth dichloride

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

1.2: 1 h / 10 - 30 °C

2.1: sulfuryl dichloride / chloroform / 0.5 h / 0 - 30 °C

With n-butyllithium; sulfuryl dichloride; In tetrahydrofuran; hexane; chloroform;

Reference yield:

: 193490-01-6
tris(2-methoxyphenyl)(2-oxopropyl)bismuthonium perchlorate

: 121899-81-8
tris(2-methoxyphenyl)bismuth dichloride

Guidance literature:: Multi-step reaction with 2 steps

1: brine / chloroform

2: ozone / dichloromethane

With brine; ozone; In dichloromethane; chloroform;
DOI:10.1039/a700379j