Tris(2-methoxyphenyl)bismuthine

Base Information

• Chemical Name: Tris(2-methoxyphenyl)bismuthine
• CAS No.: 83724-41-8
• Molecular Formula: C21H21BiO3
• Molecular Weight: 530.376
• Hs Code.: 29310099
• European Community (EC) Number: 677-577-6
• DSSTox Substance ID: DTXSID00370098
• Mol file: 83724-41-8.mol

Synonyms:Tris(2-methoxyphenyl)bismuthine;83724-41-8;Tris(2-methoxyphenyl)bismuthane;SCHEMBL1539178;tris-(2-methoxyphenyl)bismuthane;DTXSID00370098;VFWRGMGLLNCHIA-UHFFFAOYSA-N;MFCD00092705;AKOS015851741;FT-0641917;T1838;T72981

Chemical Property of Tris(2-methoxyphenyl)bismuthine

Chemical Property:

• Appearance/Colour: white to off-white crystalline powder
• Melting Point: 162-165 °C(lit.)
• PSA: 27.69000
• LogP: 4.48620
• Storage Temp.: Refrigerator
• Solubility.: almost transparency in hot Acetonitrile
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 530.12947
• Heavy Atom Count: 25
• Complexity: 334

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tris(2-methoxyphenyl)bismuthine >97.0%(T) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=CC=C1[Bi](C2=CC=CC=C2OC)C3=CC=CC=C3OC

Technology Process of Tris(2-methoxyphenyl)bismuthine

There total 20 articles about Tris(2-methoxyphenyl)bismuthine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tris(2-methoxyphenyl)bismuthane oxide + triphenylantimony (603-36-1) → tris(2-methoxyphenyl)bismuthine (83724-41-8) + triphenyl antimony oxide (4756-75-6)

Guidance literature:

In dichloromethane; Ph3Sb (2 equiv.) added to CH2Cl2 soln. of Bi compd. at room temp.; reacted for 30 min; concd. under reduced pressure; detd. by (1)H NMR spectra;

DOI:10.1021/om0494115

Reference yield: 99.0%

tris(2-methoxyphenyl)bismuthane oxide → tris(2-methoxyphenyl)bismuthine (83724-41-8)

Guidance literature:

With Ph₃P; In dichloromethane; byproducts: Ph3PO; Ph3P (2 equiv.) added to CH2Cl2 soln. of Bi compd. at room temp.; reacted for 30 min; concd. under reduced pressure; detd. by (1)H NMR spectra;

DOI:10.1021/om0494115

Reference yield: 99.0%

tris(2-methoxyphenyl)(2-oxopropyl)bismuthonium perchlorate (193490-01-6) → tris(2-methoxyphenyl)bismuthine (83724-41-8)

Guidance literature:

With brine; In chloroform; Bi-salt treating with brine excess in solvent;

DOI:10.1039/a700379j

upstream raw materials:

4-methoxyphenyl magnesium bromide

bismuth

2-methoxybenzenediazonium chloride

bismuth(III) chloride

Downstream raw materials:

tris(2-methoxyphenyl)bismuth difluoride

tris(2-methoxyphenyl)bismuth dichloride

(dimethyl sulfide)(2-methoxyphenyl)gold(I)

tetrakis(2-methoxyphenyl)bismuthonium bromide monohydrate

Refernces

• 1、 -. "CYCLOHEXANONE COMPOUNDS AND HERBICIDES COMPRISING THE SAME". Paragraph 0958-0959. . Retrieved 2014/08/19.
• 2、 Urano, Mika,Wada, Shinobu,Suzuki, Hitomi. "A novel dry route to ortho-functionalized triarylbismuthanes that are difficult to access by conventional wet routes". . p. 1202 - 1203. Retrieved 2007/10/03.