83724-41-8

Usage

Chemical Properties

white to off-white crystalline powder

InChI:InChI=1/3C7H7O.Bi/c3*1-8-7-5-3-2-4-6-7;/h3*2-5H,1H3;/rC21H21BiO3/c1-23-19-13-7-4-10-16(19)22(17-11-5-8-14-20(17)24-2)18-12-6-9-15-21(18)25-3/h4-15H,1-3H3

Upstream product

• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 7440-69-9 bismuth 
• 3425-23-8 2-methoxybenzenediazonium chloride 
• 7787-60-2 bismuth(III) chloride 
• 529-28-2 4-iodoanisol 
• 16750-63-3 2-methoxyphenylmagnesium bromide 
• 193490-01-6 tris(2-methoxyphenyl)(2-oxopropyl)bismuthonium perchlorate 
• 603-36-1 triphenylantimony 
• 121899-81-8 tris(2-methoxyphenyl)bismuth dichloride 
• 20667-12-3 silver(l) oxide 
• 313973-97-6 [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane 
• 313973-99-8 (CH₃OC₆H₄)3BiNCOC₆H₄CN 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 578-57-4 2-bromoanisole 

Downstream Products

• 121899-87-4 tris(2-methoxyphenyl)bismuth difluoride 
• 121899-81-8 tris(2-methoxyphenyl)bismuth dichloride 
• 613246-29-0 (dimethyl sulfide)(2-methoxyphenyl)gold(I) 
• 193490-13-0 tetrakis(2-methoxyphenyl)bismuthonium bromide monohydrate 
• 193489-99-5 tetrakis(2-methoxyphenyl)bismuthonium perchlorate 
• 193490-07-2 tetrakis(2-methoxyphenyl)bismuthonium tetrafluoroborate 
• 52807-17-7 4-acetyl-2'-methoxybiphenyl 
• 949468-94-4 3-chloro-6-(2-methoxyphenyl)pyridazine 
• 883-90-9 o-benzyl anisole 
• 57076-34-3 1-methoxy-2-(4-methylbenzyl)benzene 
• 117896-34-1 1-(4-fluorobenzyl)-2-methoxybenzene 
• 57076-32-1 1-methoxy-2-(2-methylbenzyl)benzene 
• 30567-87-4 2,4'-dimethoxydiphenylmethane 
• 86-26-0 2-methoxy-1,1'-biphenyl 

Relevant academic research and scientific papers

HERBICIDE COMPOSITION

There is provided a herbicidal composition containing a cyclohexanone compound represented by Formula (I) and at least one compound selected from Group A. Group A: consisting of benoxacor, cloquintocet-mexyl, cyometrinil, dichlormid, fenchlorazole-ethyl,

CYCLOHEXANONE COMPOUNDS AND HERBICIDES COMPRISING THE SAME

The present invention provides a compound having an excellent efficacy for controlling weeds. A cyclohexanone compound of the formula (I): wherein m is an integer of 1, 2 or 3; n is an integer of any one of 1 to 5; X represents CH2, O, S, S(O)

Diverse structures and remarkable oxidizing ability of triarylbismuthane oxides. Comparative study on the structure and reactivity of a series of triarylpnictogen oxides

A systematic series of triarylbismuthane oxides was prepared in order to disclose their structure and reactivity, which have been compared with those of lighter pnictogen counterparts. X-ray crystallographic analysis of tris(2-methoxyphenyl)bismuthane oxide and tris(2-methoxyphenyl)stibane oxide revealed that they exist as dimers with a flat bis(a-oxo) ring, implying that the polarized Bi+-O- and Sb+-O- bonds aggregate to attain electrostatic stabilization. In sharp contrast to their phosphorus, arsenic, and antimony counterparts, triarylbismuthane oxides are thermally unstable and possess a high oxidizing ability. In particular, the bismuthane oxides bearing ortho-substituted aryl ligands oxidized primary and secondary alcohols to aldehydes and ketones, respectively, with high efficiency under mild conditions.

A novel dry route to ortho-functionalized triarylbismuthanes that are difficult to access by conventional wet routes

When an aryl iodide bearing an electron-withdrawing group at the ortho position was milled together with bismuth shots and calcite grains in the presence of Cu powder and CuI using a laboratory ball mill, the corresponding orthofunctionalized triarylbismuthane was obtained in moderate to good yield.

Stabilized bismuthonium ylides bearing a highly cross-conjugated ylidic carbon atom: Synthesis, structures, and reactions

The reaction of iminotriaryl-λ5-bismuthanes (2; Ar3Bi=NR; R = COR″ or SO2R″) with dialkyl acetylenedicarboxylates (3; R′O2CC≡CCO2R′) has been found to afford highly stabilized bismuthonium ylides (4;

Unexpected formation of highly stabilized tetrakis-(2-alkoxyphenyl)bismuthonium salts in the oxidation of tris-(2-alkoxyphenyl)bismuthanes with iodosylbenzene

Treatment of tris-(2-alkoxyphenyl)bismuthanes 1 with iodosylbenzene in methylene dichloride at 40°C led to none of the expected bismuthane oxides 2 but, quite unexpectedly, gave tetrakis-(2-alkoxyphenyl)bismuthonium chlorides 3 in moderate to good yields. In some cases, bismuthonium formates 4 accompanied the main reaction products. Similar treatment in benzene in the presence of benzyl bromide, ethyl bromide, or 2,2,2-trifluoroethyl iodide led to the corresponding bismuthonium bromides 7 and iodides 8. Through anion exchange, a variety of bismuthonium salts including formate 4, tetrafluoroborate 11, toluene-p-sulfonate 12, bromide 7, iodide 8 and perchlorate 13 were prepared from the salt 3 in good yields. In contrast to the known tetraphenylbismuthonium salts, all of these new bismuthonium salts exhibited high thermal stability. The molecular structure of compound 7a was elucidated by X-ray analysis, where the four neighbouring oxygen atoms are found to surround the bismuth atom tetrahedrally via a weak through-space interaction with the metal, making the bismuth centre less susceptible to nucleophilic attack of the halide anion.

Fourier-transform Raman and infrared spectra and normal coordinate analysis of the triphenyl compounds and their methyl-, methoxy- and fluoro-substituted derivatives of arsenic, antimony and bismuth

The Fourier transform (FT)-Raman and infrared (IR) spectra of triphenyl-, perdeuterated triphenyl-, tris(2-methylphenyl)-, tris(3-methylphenyl)-, tris(2,4,6-trimethylphenyl)-, tris(2-methoxyphenyl)-, tris(3-methoxyphenyl)-, tris(3-fluorophenyl)- and tris(