83724-41-8

Basic information

• Product Name: TRIS(2-METHOXYPHENYL)BISMUTHINE
• Synonyms: TRIS(2-METHOXYPHENYL)BISMUTHINE;TRIS(2-METHOXYPHENYL)BISMUTHINE 98%;Tris(2-methoxyphenyl)bismuthine,98%;tris(2-methoxyphenyl)bismuthane
• CAS NO: 83724-41-8
• Molecular Formula: C₂₁H₂₁BiO₃
• Molecular Weight: 530.37
• Product Categories: Bi (Bismuth) Compounds;Classes of Metal Compounds;Semimetal Compounds;Bismuth;Precursors by Metal;Vapor Deposition Precursors
• Mol File: 83724-41-8.mol
• Article Data: 8

Chemical Properties

• Melting Point: 162-165 °C(lit.)
• Appearance: /solid
• Storage Temp.: Refrigerator
• Solubility: almost transparency in hot Acetonitrile
• CAS DataBase Reference: TRIS(2-METHOXYPHENYL)BISMUTHINE(CAS DataBase Reference)
• NIST Chemistry Reference: TRIS(2-METHOXYPHENYL)BISMUTHINE(83724-41-8)
• EPA Substance Registry System: TRIS(2-METHOXYPHENYL)BISMUTHINE(83724-41-8)

Safety Data

• Safety Statements: 24/25
• WGK Germany: 3
• Hazardous Substances Data: 83724-41-8(Hazardous Substances Data)

Usage

Chemical Properties

white to off-white crystalline powder

InChI:InChI=1/3C7H7O.Bi/c3*1-8-7-5-3-2-4-6-7;/h3*2-5H,1H3;/rC21H21BiO3/c1-23-19-13-7-4-10-16(19)22(17-11-5-8-14-20(17)24-2)18-12-6-9-15-21(18)25-3/h4-15H,1-3H3

Upstream product

• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 7440-69-9 bismuth 
• 3425-23-8 2-methoxybenzenediazonium chloride 
• 7787-60-2 bismuth(III) chloride 
• 529-28-2 4-iodoanisol 
• 16750-63-3 2-methoxyphenylmagnesium bromide 
• 193490-01-6 tris(2-methoxyphenyl)(2-oxopropyl)bismuthonium perchlorate 
• 603-36-1 triphenylantimony 
• 121899-81-8 tris(2-methoxyphenyl)bismuth dichloride 
• 20667-12-3 silver(l) oxide 
• 578-57-4 2-bromoanisole 
• 313973-99-8 (CH₃OC₆H₄)3BiNCOC₆H₄CN 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 313973-97-6 [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane 

Downstream Products

• 193490-13-0 tetrakis(2-methoxyphenyl)bismuthonium bromide monohydrate 
• 2314-77-4 N-(2-methoxyphenyl)phthalimide 
• 86-26-0 2-methoxy-1,1'-biphenyl 
• 113547-30-1 2’-methoxy-[1,1’-biphenyl]-4-carbonitrile 
• 52807-17-7 4-acetyl-2'-methoxybiphenyl 
• 421553-62-0 2'-methoxy-[1,1'-biphenyl]-4-carboxaldehyde 
• 93321-11-0 1-(2-methoxyphenyl)naphthalene 
• 30567-87-4 2,4'-dimethoxydiphenylmethane 
• 57076-32-1 1-methoxy-2-(2-methylbenzyl)benzene 
• 117896-34-1 1-(4-fluorobenzyl)-2-methoxybenzene 
• 57076-34-3 1-methoxy-2-(4-methylbenzyl)benzene 
• 883-90-9 o-benzyl anisole 
• 949468-94-4 3-chloro-6-(2-methoxyphenyl)pyridazine 
• 193490-07-2 tetrakis(2-methoxyphenyl)bismuthonium tetrafluoroborate 

Relevant articles and documents

HERBICIDE COMPOSITION

There is provided a herbicidal composition containing a cyclohexanone compound represented by Formula (I) and at least one compound selected from Group A. Group A: consisting of benoxacor, cloquintocet-mexyl, cyometrinil, dichlormid, fenchlorazole-ethyl,

Diverse structures and remarkable oxidizing ability of triarylbismuthane oxides. Comparative study on the structure and reactivity of a series of triarylpnictogen oxides

A systematic series of triarylbismuthane oxides was prepared in order to disclose their structure and reactivity, which have been compared with those of lighter pnictogen counterparts. X-ray crystallographic analysis of tris(2-methoxyphenyl)bismuthane oxide and tris(2-methoxyphenyl)stibane oxide revealed that they exist as dimers with a flat bis(a-oxo) ring, implying that the polarized Bi+-O- and Sb+-O- bonds aggregate to attain electrostatic stabilization. In sharp contrast to their phosphorus, arsenic, and antimony counterparts, triarylbismuthane oxides are thermally unstable and possess a high oxidizing ability. In particular, the bismuthane oxides bearing ortho-substituted aryl ligands oxidized primary and secondary alcohols to aldehydes and ketones, respectively, with high efficiency under mild conditions.

Dimeric triarylbismuthane oxide: A novel efficient oxidant for the conversion of alcohols to carbonyl compounds

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