Methanesulfonic acid (S)-phenyl-((4R,5R,6S)-2,2,5,6-tetramethyl-[1,3]dioxan-4-yl)-methyl ester

Base Information

Chemical Name:Methanesulfonic acid (S)-phenyl-((4R,5R,6S)-2,2,5,6-tetramethyl-[1,3]dioxan-4-yl)-methyl ester
CAS No.:1026259-49-3
Molecular Formula:C₁₆H₂₄O₅S
Molecular Weight:328.43
Hs Code.:

Synonyms:Methanesulfonic acid (S)-phenyl-((4R,5R,6S)-2,2,5,6-tetramethyl-[1,3]dioxan-4-yl)-methyl ester

Suppliers and Price of Methanesulfonic acid (S)-phenyl-((4R,5R,6S)-2,2,5,6-tetramethyl-[1,3]dioxan-4-yl)-methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methanesulfonic acid (S)-phenyl-((4R,5R,6S)-2,2,5,6-tetramethyl-[1,3]dioxan-4-yl)-methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methanesulfonic acid (S)-phenyl-((4R,5R,6S)-2,2,5,6-tetramethyl-[1,3]dioxan-4-yl)-methyl ester

There total 6 articles about Methanesulfonic acid (S)-phenyl-((4R,5R,6S)-2,2,5,6-tetramethyl-[1,3]dioxan-4-yl)-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 191410-59-0
(2R,3R,4S)-1-benzyloxy-3-methyl-2,4-pentanediol

: 1026259-49-3
Methanesulfonic acid (S)-phenyl-((4R,5R,6S)-2,2,5,6-tetramethyl-[1,3]dioxan-4-yl)-methyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / camphorsulfonic acid / CH₂Cl₂ / 1 h / 0 °C

2: 97 percent / H₂ / Pd/C / ethyl acetate / 2 h / 20 °C / 760.05 Torr

3: SO₃-pyridine complex; Et₃N / CH₂Cl₂; dimethylsulfoxide / 1 h / 0 °C

4: 485 mg / diethyl ether / 1 h / 0 °C

5: Et₃N / CH₂Cl₂ / 0.5 h / 0 °C

With pyridine-SO₃ complex; camphor-10-sulfonic acid; hydrogen; triethylamine; palladium on activated charcoal; In diethyl ether; dichloromethane; dimethyl sulfoxide; ethyl acetate; 4: Grignard addition;
DOI:10.1021/jo010131y

Reference yield:

: 191410-60-3
(4R,5R,6S)-4-Benzyloxymethyl-2,2,5,6-tetramethyl-[1,3]dioxane

: 1026259-49-3
Methanesulfonic acid (S)-phenyl-((4R,5R,6S)-2,2,5,6-tetramethyl-[1,3]dioxan-4-yl)-methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 97 percent / H₂ / Pd/C / ethyl acetate / 2 h / 20 °C / 760.05 Torr

2: SO₃-pyridine complex; Et₃N / CH₂Cl₂; dimethylsulfoxide / 1 h / 0 °C

3: 485 mg / diethyl ether / 1 h / 0 °C

4: Et₃N / CH₂Cl₂ / 0.5 h / 0 °C

With pyridine-SO₃ complex; hydrogen; triethylamine; palladium on activated charcoal; In diethyl ether; dichloromethane; dimethyl sulfoxide; ethyl acetate; 3: Grignard addition;
DOI:10.1021/jo010131y