trans-3-Methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethyl-pyrrolidin-1-oxyl

Base Information

Chemical Name:trans-3-Methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethyl-pyrrolidin-1-oxyl
CAS No.:119580-75-5
Molecular Formula:C₁₁H₁₉N₂O₅
Molecular Weight:259.282
Hs Code.:
Mol file:119580-75-5.mol

Synonyms:1-Pyrrolidinyloxy,3-(methoxycarbonyl)-2,2,5,5-tetramethyl-4-(nitromethyl)-, trans-

Suppliers and Price of trans-3-Methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethyl-pyrrolidin-1-oxyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
trans-3-Methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethyl-pyrrolidin-1-oxyl
250mg
$ 1100.00

American Custom Chemicals Corporation
TRANS-3-METHOXYCARBONYL-2,2,5,5-TETRAMETHYL-4-NITROMETHYL-PYRROLIDIN-1-OXYL 95.00%
250MG
$ 1732.50

American Custom Chemicals Corporation
TRANS-3-METHOXYCARBONYL-2,2,5,5-TETRAMETHYL-4-NITROMETHYL-PYRROLIDIN-1-OXYL 95.00%
25MG
$ 721.88

Total 2 raw suppliers

Chemical Property of trans-3-Methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethyl-pyrrolidin-1-oxyl

Chemical Property:

Melting Point:116-118掳C
PSA：75.36000
LogP:1.34790

Purity/Quality:

97% ^*data from raw suppliers

trans-3-Methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethyl-pyrrolidin-1-oxyl ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses A spin label A spin label.

Technology Process of trans-3-Methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethyl-pyrrolidin-1-oxyl

There total 1 articles about trans-3-Methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethyl-pyrrolidin-1-oxyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 75-52-5
nitromethane

: 2154-32-7
methyl 1-oxyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-3-carboxylate radical

: 119580-75-5
trans-3-methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethylpyrrolidin-1-oxyl

Guidance literature:: With 1,5-diazabicyclo[5.4.0]-undec-7-ene; In acetonitrile; at 50 ℃; for 8h;

Reference yield:

: 119580-75-5
trans-3-methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethylpyrrolidin-1-oxyl

: trans-4--3-carboxy-2,2,5,5-tetramethylpyrrolidin-1-oxyl

Guidance literature:: Multi-step reaction with 3 steps

1: 1) ammonium formate 2) PbO₂, O₂ / 1) 10percent Pd/C / 1) MeOH, 40 deg C, 1 h 2) CHCl₃

2: 75 percent / Et₃N / ethanol / 6 h / 50 °C

3: 76 percent / NaOH / methanol; H₂O / 1 h / 40 °C

With sodium hydroxide; oxygen; ammonium formate; lead dioxide; triethylamine; palladium on activated charcoal; In methanol; ethanol; water;

Reference yield:

: 119580-75-5
trans-3-methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethylpyrrolidin-1-oxyl

: trans-4--3-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-oxyl

Guidance literature:: Multi-step reaction with 2 steps

1: 1) ammonium formate 2) PbO₂, O₂ / 1) 10percent Pd/C / 1) MeOH, 40 deg C, 1 h 2) CHCl₃

2: 75 percent / Et₃N / ethanol / 6 h / 50 °C

With oxygen; ammonium formate; lead dioxide; triethylamine; palladium on activated charcoal; In ethanol;