trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl Radical

Base Information

Chemical Name:trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl Radical
CAS No.:229621-04-9
Molecular Formula:C₁₁H₁₈NO₄
Molecular Weight:228.268
Hs Code.:
Mol file:229621-04-9.mol

Synonyms:trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl Radical

Suppliers and Price of trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl Radical

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl radical
5mg
$ 425.00

TRC
trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxylRadical
50mg
$ 675.00

TRC
trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxylRadical
5mg
$ 100.00

American Custom Chemicals Corporation
TRANS-3-FORMYL-4-METHOXYCARBONYL-2,2,5,5-TETRAMETHYLPYRROLIDIN-1-YLOXYL 95.00%
100MG
$ 1732.50

American Custom Chemicals Corporation
TRANS-3-FORMYL-4-METHOXYCARBONYL-2,2,5,5-TETRAMETHYLPYRROLIDIN-1-YLOXYL 95.00%
10MG
$ 721.88

Total 2 raw suppliers

Chemical Property of trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl Radical

Chemical Property:

Melting Point:77-79°C
PSA：46.61000
LogP:0.74690
Storage Temp.:-20°C Freezer, Under Inert Atmosphere
Solubility.:Acetone, Chloroform, Dichloromethane, Methanol

Purity/Quality:

99% ^*data from raw suppliers

trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl radical ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses A spin label A spin label.

Technology Process of trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl Radical

There total 1 articles about trans-3-Formyl-4-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl Radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 119580-75-5
trans-3-methoxycarbonyl-2,2,5,5-tetramethyl-4-nitromethylpyrrolidin-1-oxyl

: 229621-04-9
trans-4-Formyl-3-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl radical

: trans-3-Methoxycarbonyl-4-acetyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl biradical

Guidance literature:: With potassium hydroxide; potassium permanganate; magnesium sulfate; Yield given; Multistep reaction. Yields of byproduct given; 1.) MeOH, 0 deg C, 15 min, 2.) MeOH, H₂O, 0 deg C, 2 h;
DOI:10.1055/s-1999-3502

Reference yield: 80.0%

: 229621-04-9
trans-4-Formyl-3-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl radical

: 229621-07-2
trans-3,4-Bis(hydroxymethyl)-2,2,5,5-tetramethylpyrrolidin-1-yloxyl radical

Guidance literature:: With sodium tetrahydroborate; In ethanol; for 0.5h; Ambient temperature;
DOI:10.1055/s-1999-3502

Reference yield:

: 229621-04-9
trans-4-Formyl-3-methoxycarbonyl-2,2,5,5-tetramethylpyrrolidin-1-yloxyl radical

: 229621-21-0
2,5-Dihydro-3,4-bis(methanesulfonylthiomethyl)-2,2,5,5-tetramethyl-1H-pyrrol-1-yloxyl radical

Guidance literature:: Multi-step reaction with 6 steps

1: 80 percent / NaBH₄ / ethanol / 0.5 h / Ambient temperature

2: Et₃N / CH₂Cl₂ / 1 h / Ambient temperature

3: NaI / tetrahydrofuran / 48 h / Heating

4: 82 percent / NaOH, H₂O / ethanol / 0.5 h / 78 °C

5: 1.) HCl, 2.) Br₂ / 1.) EtOH, 78 deg C, 30 min, 2.) CHCl₃, 61 deg C, 30 min

6: 58 percent / ethanol; CH₂Cl₂ / 0.5 h / Heating

With hydrogenchloride; sodium hydroxide; sodium tetrahydroborate; water; bromine; triethylamine; sodium iodide; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1055/s-1999-3502