3-methyl-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

Base Information

• Chemical Name: 3-methyl-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide
• CAS No.: 1377585-41-5
• Molecular Formula: C₁₅H₁₅NO₂S
• Molecular Weight: 273.356
• Mol file: 1377585-41-5.mol

Synonyms:3-methyl-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

Chemical Property of 3-methyl-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 3-methyl-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

There total 14 articles about 3-methyl-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

S-methyl-S-phenylsulfoximine (4381-25-3) + 3-Methylbenzoyl chloride (1711-06-4) → 3-methyl-N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)benzamide (1377585-41-5)

Guidance literature:

S-methyl-S-phenylsulfoximine; With sodium hydride; In dichloromethane; mineral oil; at 20 ℃; Inert atmosphere;

3-Methylbenzoyl chloride; In dichloromethane; mineral oil; at 0 - 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/chem.201200092

Reference yield: 90.0%

→ 3-methyl-N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)benzamide (1377585-41-5)

Guidance literature:

With tert.-butylhydroperoxide; dipotassium peroxodisulfate; In acetonitrile; at 20 ℃; for 12h; Sealed tube; Irradiation;

Reference yield: 89.0%

S-methyl-S-phenylsulfoximine (4381-25-3) + m-tolyl aldehyde (620-23-5) → 3-methyl-N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)benzamide (1377585-41-5)

Guidance literature:

With tert.-butylhydroperoxide; dipotassium peroxodisulfate; In acetonitrile; at 20 ℃; for 12h; Irradiation;

DOI:10.1007/s11426-019-9499-5

upstream raw materials:

methyl-phenyl-thioether

racemic methyl phenyl sulfoxide

S-methyl-S-phenylsulfoximine

3-Methylbenzoyl chloride

Downstream raw materials:

N-[2-acetoxy-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

N-[2-hydroxy-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

N-[2,6-diacetoxy-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

N-[2-(4'-methylbenzenesulfonamido)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine