Technology Process of cis-2-methoxy-5-tosyl-4b,5,6,10b,11,12-hexahydrobenzophenanthridine
There total 6 articles about cis-2-methoxy-5-tosyl-4b,5,6,10b,11,12-hexahydrobenzophenanthridine which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
trifluoroacetic acid;
In
dichloromethane;
at 20 ℃;
for 48h;
- Guidance literature:
-
Multi-step reaction with 4 steps
1: SOCl2 / Heating
2: AlCl3 / CH2Cl2 / 1 h / 20 °C
3: 46 percent / diethyl ether; CH2Cl2 / 24 h / 20 °C
4: 70 percent / trifluoroacetic acid / CH2Cl2 / 48 h / 20 °C
With
aluminium trichloride; thionyl chloride; trifluoroacetic acid;
In
diethyl ether; dichloromethane;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.) K2CO3, NaI, 2.) 10percent aq. NaOH / 1.) acetone, reflux, 6 h, 2.) 50 deg C, 4 h
2: SOCl2 / Heating
3: AlCl3 / CH2Cl2 / 1 h / 20 °C
4: 46 percent / diethyl ether; CH2Cl2 / 24 h / 20 °C
5: 70 percent / trifluoroacetic acid / CH2Cl2 / 48 h / 20 °C
With
sodium hydroxide; aluminium trichloride; thionyl chloride; potassium carbonate; trifluoroacetic acid; sodium iodide;
In
diethyl ether; dichloromethane;
