formic acid triphenylsilanyl ester

Base Information

• Chemical Name: formic acid triphenylsilanyl ester
• CAS No.: 18670-64-9
• Molecular Formula: C₁₉H₁₆O₂Si
• Molecular Weight: 304.42
• Mol file: 18670-64-9.mol

Synonyms:formic acid triphenylsilanyl ester

Chemical Property of formic acid triphenylsilanyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of formic acid triphenylsilanyl ester

There total 3 articles about formic acid triphenylsilanyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

carbon dioxide (124-38-9,18923-20-1) + HSiPh3 (789-25-3) → formic acid triphenylsilanyl ester (18670-64-9)

Guidance literature:

HSiPh₃; With dirhodium tetraacetate; potassium carbonate; In acetonitrile; Schlenk technique; Inert atmosphere;

carbon dioxide; In acetonitrile; at 70 ℃; for 24h; Schlenk technique;

DOI:10.1016/j.molcata.2012.10.014

Reference yield:

triphenyl-silanecarboxylic acid (18670-88-7) → formic acid triphenylsilanyl ester (18670-64-9) + triphenylhydroxysilane (791-31-1)

Guidance literature:

DOI:10.1021/ja01623a042

Reference yield:

carbon dioxide (1111-72-4) + HSiPh3 (789-25-3) → formic acid triphenylsilanyl ester (18670-64-9)

Guidance literature:

With [(N,N'-bis(diisopropylphosphino)-2,6-diaminopyridine)Mn(CO)₂H]; In dimethylsulfoxide-d6; at 80 ℃; for 24h; under 750.075 Torr;

DOI:10.1021/acscatal.8b04106

upstream raw materials:

triphenyl-silanecarboxylic acid

carbon dioxide

HSiPh₃

carbon dioxide