3-Cyanobenzylzinc bromide

Base Information

Chemical Name:3-Cyanobenzylzinc bromide
CAS No.:117269-72-4
Molecular Formula:C8H6 Br N Zn
Molecular Weight:261.436
Hs Code.:
DSSTox Substance ID:DTXSID301303183
Mol file:117269-72-4.mol

Synonyms:117269-72-4;3-cyanobenzylzinc bromide;bromozinc(1+);3-methanidylbenzonitrile;MFCD01311398;Zinc, bromo[(3-cyanophenyl)methyl]-;3-Cyanobenzylzinc bromide 0.5 M in Tetrahydrofuran;(3-cyanobenzyl)zinc(II) bromide;3-CYANOBENZYLZINCBROMIDE;DTXSID301303183;AKOS015888864;BROMO[(3-CYANOPHENYL)METHYL]ZINC;3-Cyanobenzylzinc bromide, 0.50 M in THF;3-Cyanobenzylzinc bromide, 0.5M in tetrahydrofuran;J-003545

Suppliers and Price of 3-Cyanobenzylzinc bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
3-Cyanobenzylzinc bromide solution 0.5 M in THF
50ml
$ 263.00

Rieke Metals
3-Cyanobenzylzincbromide
100mL
$ 503.00

Rieke Metals
3-Cyanobenzylzincbromide
50mL
$ 307.00

American Custom Chemicals Corporation
3-CYANOBENZYLZINC BROMIDE 95.00%
1L
$ 9009.00

American Custom Chemicals Corporation
3-CYANOBENZYLZINC BROMIDE 95.00%
500ML
$ 5775.00

American Custom Chemicals Corporation
3-CYANOBENZYLZINC BROMIDE 95.00%
100ML
$ 2841.30

Total 12 raw suppliers

Chemical Property of 3-Cyanobenzylzinc bromide

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:1℉
PSA：23.79000
Density:0.966g/mLat25℃
LogP:-1.23182
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:258.89750
Heavy Atom Count:11
Complexity:140

Purity/Quality:

98%,99%, ^*data from raw suppliers

3-Cyanobenzylzinc bromide solution 0.5 M in THF ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,Xn
Statements: 19-22-36/38-40-36/37-14-11
Safety Statements: 16-26-33-36-36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[CH2-]C1=CC(=CC=C1)C#N.[Zn+]Br

Technology Process of 3-Cyanobenzylzinc bromide

There total 3 articles about 3-Cyanobenzylzinc bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 28188-41-2
m-(bromomethyl)benzonitrile

: 117269-72-4
(3-cyano-benzyl)zinc(II) bromide

Guidance literature:: With chloro-trimethyl-silane; iodine; ethylene dibromide; lithium chloride; zinc; In tetrahydrofuran; at 25 ℃; for 3h;
DOI:10.1080/00397911.2019.1663540

Reference yield:

: 28188-41-2
m-(bromomethyl)benzonitrile

: 7440-66-6
zinc

: 117269-72-4
(3-cyano-benzyl)zinc(II) bromide

Guidance literature:: zinc; With ethylene dibromide; In tetrahydrofuran; at 65 ℃; for 0.0833333h; Inert atmosphere;

m-(bromomethyl)benzonitrile; In tetrahydrofuran; at 0 ℃; for 10h; Inert atmosphere;
DOI:10.1021/jo401640c

Reference yield:

: 117269-72-4
(3-cyano-benzyl)zinc(II) bromide

Guidance literature:: With chloro-trimethyl-silane; In tetrahydrofuran; ethylene dibromide; at 65 ℃; for 0.5h; Inert atmosphere;

In tetrahydrofuran; ethylene dibromide; at 20 ℃; for 1h; Inert atmosphere;