2,5-dimethyl-3,4-di-iso-propyl-3,4-hexanediol

Base Information

• Chemical Name: 2,5-dimethyl-3,4-di-iso-propyl-3,4-hexanediol
• CAS No.: 54580-24-4
• Molecular Formula: C₁₄H₃₀O₂
• Molecular Weight: 230.391
• Mol file: 54580-24-4.mol

Synonyms:2,5-dimethyl-3,4-di-iso-propyl-3,4-hexanediol

Chemical Property of 2,5-dimethyl-3,4-di-iso-propyl-3,4-hexanediol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,5-dimethyl-3,4-di-iso-propyl-3,4-hexanediol

There total 4 articles about 2,5-dimethyl-3,4-di-iso-propyl-3,4-hexanediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4-dimethylpentan-3-one (565-80-0) → 2,4-dimethyl-3-pentanol (600-36-2) + 2,4-dimethyl-2-pentene (625-65-0) + 2,5-dimethyl-3,4-di-iso-propyl-3,4-hexanediol (54580-24-4) + diisopropylidene diisopropane (7090-88-2)

Guidance literature:

With titanium tetrachloride; lithium; In tetrahydrofuran-d8; at 20 ℃; for 24h; Further Variations:; Reagents; molar ratio; Product distribution;

DOI:10.1002/1521-3765(20010716)7:14<3043::AID-CHEM3043>3.0.CO;2-D

Reference yield:

C14H28O2(2-)*2Li(1+) → 2,4-dimethylpentane (108-08-7) + 2,4-dimethyl-3-pentanol (600-36-2) + 2,4-dimethyl-2-pentene (625-65-0) + 2,5-dimethyl-3,4-di-iso-propyl-3,4-hexanediol (54580-24-4) + diisopropylidene diisopropane (7090-88-2)

Guidance literature:

With titanium tetrachloride; lithium; In tetrahydrofuran; at 20 ℃; for 10h; Product distribution; other reagent;

DOI:10.1002/anie.199723801

Reference yield:

C14H28O2(2-)*2Li(1+) → 2,4-dimethyl-3-pentanol (600-36-2) + 2,5-dimethyl-3,4-di-iso-propyl-3,4-hexanediol (54580-24-4) + diisopropylidene diisopropane (7090-88-2)

Guidance literature:

With uranium(IV) chloride; lithium; In tetrahydrofuran; at 20 ℃; for 10h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1002/anie.199723801

upstream raw materials:

isopropyllithium

2,4-dimethylpentan-3-one

Refernces

• 1、 Villiers, Claude,Ephritikhine, Michel. "Reactions of aliphatic ketones R2CO (R = Me, Et, iPr, and tBu) with the MCl4/Li(Hg) system (M = U or Ti): Mechanistic analogies between the McMurry, Wittig, and Clemmensen reactions". . p. 3043 - 3051. Retrieved 2007/10/03.